(2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene

Base Information

• Chemical Name: (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene
• CAS No.: 186817-78-7
• Molecular Formula: C₁₆H₂₁ClS
• Molecular Weight: 280.862
• Mol file: 186817-78-7.mol

Synonyms:(2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene

Chemical Property of (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene

There total 3 articles about (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,1-dimethyl-2,3-bis(methylene)cyclohexane (60714-17-2) + benzenesulfenyl chloride (931-59-9) → (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene (186817-78-7)

Guidance literature:

In dichloromethane; -70 deg C to RT; 3 h, reflux;

DOI:10.1139/v96-207

Reference yield:

thiophenol (108-98-5) → (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene (186817-78-7)

Guidance literature:

Multi-step reaction with 2 steps

1: N-chlorosuccinimide / CH₂Cl₂

2: CH₂Cl₂ / -70 - 20 °C

With N-chloro-succinimide; In dichloromethane;

DOI:10.1139/v96-207

Reference yield:

1,1-dimethyl-2,3-bis(methylene)cyclohexane (60714-17-2) + benzenesulfenyl chloride (931-59-9) → (1-Chloro-2,2-dimethyl-6-methylene-cyclohexylmethylsulfanyl)-benzene + (2-Chloromethyl-6,6-dimethyl-cyclohex-1-enylmethylsulfanyl)-benzene (186817-78-7)

Guidance literature:

In dichloromethane; at -70 - 20 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1139/v96-207

upstream raw materials:

1,1-dimethyl-2,3-bis(methylene)cyclohexane

benzenesulfenyl chloride

thiophenol

Downstream raw materials:

{[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]thio}benzene