S-phenyl ethylcarbamothioate

Base Information

• Chemical Name: S-phenyl ethylcarbamothioate
• CAS No.: 14467-74-4
• Molecular Formula: C9H11 N O S
• Molecular Weight: 181.258
• Mol file: 14467-74-4.mol

Synonyms:Carbamicacid, ethylthio-, S-phenyl ester (6CI,8CI); Carbamothioic acid, ethyl-,S-phenyl ester (9CI); S-b-Phenylthioethyl thiocarbamate

Chemical Property of S-phenyl ethylcarbamothioate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 57.89000
• Density: 1.14g/cm³
• LogP: 2.71260

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-phenyl ethylcarbamothioate

There total 5 articles about S-phenyl ethylcarbamothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

thiophenol (108-98-5) + ethyl isocyanate (109-90-0) → S-phenyl N-ethylthiocarbamate (14467-74-4)

Guidance literature:

at 25 ℃; for 1.5h;

DOI:10.1007/s00706-007-0762-7

Reference yield: 73.0%

S-Phenyl benzenethiosulfonate (1212-08-4) + N-formylethylamine (627-45-2) → S-phenyl N-ethylthiocarbamate (14467-74-4)

Guidance literature:

With tert.-butylhydroperoxide; rhodamine B; In water; at 20 ℃; for 12h; Irradiation; Inert atmosphere;

DOI:10.1039/d1ob01592c

Reference yield:

phenyl chlorothioformate (13464-19-2) + ethylamine (75-04-7,85404-22-4) → S-phenyl N-ethylthiocarbamate (14467-74-4)

Guidance literature:

With 1,4-dioxane;

DOI:10.1021/ja01110a037

upstream raw materials:

phenyl chlorothioformate

ethylamine

thiophenol

ethyl isocyanate

Downstream raw materials:

N,N'-diethylurea

1-Ethyl-3-(4-methyl-benzyl)-urea

1-(4-Chloro-benzyl)-3-ethyl-urea

Chloromethyl-ethyl-thiocarbamic acid S-phenyl ester

Refernces

• 1、 Bi, Wen-Zhu,Zhang, Wen-Jie,Li, Zi-Jie,He, Yuan-Hao,Feng, Su-Xiang,Geng, Yang,Chen, Xiao-Lan,Qu, Ling-Bo. "Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides". supporting information. p. 8701 - 8705. Retrieved 2021/10/22.