3-methyl-5-propan-2-yl-cyclohex-2-en-1-one

Base Information

• Chemical Name: 3-methyl-5-propan-2-yl-cyclohex-2-en-1-one
• CAS No.: 535-86-4
• Molecular Formula: C10H16O
• Molecular Weight: 152.2334
• Mol file: 535-86-4.mol

Synonyms:2-Cyclohexen-1-one, 3-methyl-5-(1-methylethyl)-;m-Menth-6-en-5-one;Homocamfin;Hexeton;Hexetone;

Chemical Property of 3-methyl-5-propan-2-yl-cyclohex-2-en-1-one

Chemical Property:

• Vapor Pressure: 0.0311mmHg at 25°C
• Boiling Point: 244°Cat760mmHg
• Flash Point: 90.9°C
• PSA: 17.07000
• Density: 0.915g/cm³
• LogP: 2.56780

Purity/Quality:

99% ,99.9%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 3-methyl-5-propan-2-yl-cyclohex-2-en-1-one

There total 16 articles about 3-methyl-5-propan-2-yl-cyclohex-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-Methyl-6-(1-methylethyl)-4-oxo-2-cyclohexen-1-carbonsaeure-ethylester (24079-95-6) → 3-methyl-5-(1-methylethyl)-2-cyclohexen-1-one (28587-71-5,112710-42-6,535-86-4)

Guidance literature:

Reference yield: 83.0%

diethyl 4-isopropyl-1,2,6-trimethyl-1,4-dihydropyridine-3,5-dicarboxylate (30594-34-4) → 3-methyl-5-(1-methylethyl)-2-cyclohexen-1-one (28587-71-5,112710-42-6,535-86-4)

Guidance literature:

With hydrogenchloride; In ethanol; for 30h; Heating;

DOI:10.1007/s10593-007-0006-0

Reference yield:

4-iso-propyl-2,6-heptanedione (112632-68-5) → C10H16O (1089183-29-8,112710-42-6,535-86-4) + 3-methyl-5-isopropyl-2-cyclohexen-1-one (112710-42-6,535-86-4)

Guidance literature:

With 9-epi-9-amino-9-deoxyquinine; acetic acid; In toluene; at -15 ℃; for 48 - 96h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/anie.200802497

upstream raw materials:

ethyl acetoacetate

isobutyraldehyde

2-Methyl-6-(1-methylethyl)-4-oxo-2-cyclohexen-1-carbonsaeure-ethylester

sulfuric acid

Downstream raw materials:

m-menth-6-en-5-ylamine

(3R,5R)-3-(4-Hydroxy-1-methylene-butyl)-5-isopropyl-3-methyl-cyclohexanone

1,3-Dimethyl-5-isopropyl-cyclohexadien-(1,3)

3-isopropyl-1-methyl-5-oxo-cyclohexanecarbonitrile