Technology Process of (CO)5WN(C6H5)N(C6H5)C(CH3)(OCH3)
There total 1 articles about (CO)5WN(C6H5)N(C6H5)C(CH3)(OCH3) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
benzene;
addn. of tungsten-carbene to cis-azobenzene in solvent, soln. turnes dark red immediately, 2-3 min in the dark; evapn. (vac.), washing of residue with pentane until the soln. is clear, drying of residue (vac., 2-3 min);
DOI:10.1021/ja00013a024
- Guidance literature:
-
With
triphenylphosphine;
In
not given;
Irradiation (UV/VIS); thermal or photochemical;
Kinetics;
DOI:10.1021/ja00202a048
- Guidance literature:
-
In
(2)H8-toluene;
byproducts: (C6H5)NC(OCH3)CH3, CH3OC(O)N(C6H5)H, C6H5NNC6H5; Irradiation (UV/VIS); dissoln. of W-complex in toluene-d(8), photolyses at room temp. for 3 h, NMR tube, medium-pressure Hg vapor lamp); inert atmosphere techniques; products not isolated, detd. by NMR, GC/MS; nitrene-complex is not isolated or detd. spect., detn. of this product by further react. with org. compds.;
DOI:10.1021/ja00013a024
