methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

Base Information

Chemical Name:methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside
CAS No.:118117-24-1
Molecular Formula:C₁₇H₁₈O₆S
Molecular Weight:350.392
Hs Code.:

Synonyms:methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

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Technology Process of methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

There total 6 articles about methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 463-71-8
thiophosgene

: 118117-30-9
methyl-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

: 118117-24-1
methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

Guidance literature:: With 1H-imidazole; In chloroform; for 12.5h; Heating;
DOI:10.1016/S0040-4020(01)85970-6

Reference yield:

: 68366-59-6
(2R,4aR,6S,7R,8aR)-6-methoxy-8-oxo-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine

: 118117-24-1
methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / tetrahydrofuran / 0.5 h / -78 - -75 °C

2: 92 percent / NaOH / methanol / 0.17 h / Ambient temperature

3: 87 percent / imidazole / CHCl₃ / 12.5 h / Heating

With 1H-imidazole; sodium hydroxide; In tetrahydrofuran; methanol; chloroform;
DOI:10.1016/S0040-4020(01)85970-6

Reference yield:

: 100-52-7
benzaldehyde

: 118117-24-1
methyl-2,3-O-thionocarbonate-3-vinyl-4,6-O-benzylidene-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 75 percent / ZnCl₂ / CHCl₃

2: 1.) Bu₂SnO, 2.) Et₃N / 1.) MeOH, benzene, reflux, 2.) 10 deg C to RT

3: 89 percent / (COCl)2, Et₃N / CH₂Cl₂; dimethylsulfoxide / 0.5 h / -78 °C

4: 77 percent / tetrahydrofuran / 0.5 h / -78 - -75 °C

5: 92 percent / NaOH / methanol / 0.17 h / Ambient temperature

6: 87 percent / imidazole / CHCl₃ / 12.5 h / Heating

With 1H-imidazole; sodium hydroxide; oxalyl dichloride; di(n-butyl)tin oxide; triethylamine; zinc(II) chloride; In tetrahydrofuran; methanol; dichloromethane; chloroform; dimethyl sulfoxide;
DOI:10.1016/S0040-4020(01)85970-6