(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

Base Information

Chemical Name:(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal
CAS No.:1217869-89-0
Molecular Formula:C₂₅H₄₄O₅Si
Molecular Weight:452.707
Hs Code.:

Synonyms:(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

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Technology Process of (3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

There total 1 articles about (3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1217869-97-0
(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanenitrile

: 1217869-89-0
(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

Guidance literature:: (3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanenitrile; With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 ℃;

With water; rochelle salt; In hexane; dichloromethane;
DOI:10.1055/s-0029-1217099

Reference yield: 96.0%

: 1217869-89-0
(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

: 24470-78-8
isopropyltriphenylphosphonium iodide

: 1217870-00-2
tert-butyl[(3R,4R,5R,6S)-5-methoxy-1-(4-methoxybenzyloxy)-4,6,9-trimethyldec-8-en-3-yloxy]dimethylsilane

Guidance literature:: isopropyltriphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at -10 ℃;

(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal; In tetrahydrofuran; hexane; at -78 ℃;
DOI:10.1055/s-0029-1217099

Reference yield:

: 1217869-89-0
(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal

: 4736-60-1
ethyltriphenylphosphonium iodide

: 866529-95-5
(E,3R,4S,5R,6S)-3-(tert-butyldimethylsilanyloxy)-5-methoxy-1-(4-methoxybenzyloxy)-4,6-dimethyl-8-decene

: tert-butyl[(3R,4R,5R,6S,Z)-5-methoxy-1-(4-methoxybenzyloxy)-4,6-dimethyldec-8-en-3-yloxy]dimethylsilane

Guidance literature:: ethyltriphenylphosphonium iodide; With sodium hexamethyldisilazane; In tetrahydrofuran; at -10 ℃;

(3S,4R,5R,6R)-6-(tert-butyldimethylsilyloxy)-4-methoxy-8-(4-methoxybenzyloxy)-3,5-dimethyloctanal; With sodium hexamethyldisilazane; In tetrahydrofuran; methanol; at -78 - 20 ℃; optical yield given as %de;
DOI:10.1055/s-0029-1217099