bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate
• CAS No.: 1000015-88-2
• Molecular Formula: CF₃O₃S*C₁₆H₁₈I
• Molecular Weight: 486.294
• Mol file: 1000015-88-2.mol

Synonyms:bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate

Chemical Property of bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate

There total 2 articles about bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trifluorormethanesulfonic acid (1493-13-6) + bis(acetyloxy)-(2,5-dimethylphenyl)-λ3-iodane (41018-54-6) + 2,5-dimethylphenyl boronic acid (85199-06-0) → bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate (1000015-88-2)

Guidance literature:

bis(acetyloxy)-(2,5-dimethylphenyl)-λ3-iodane; 2,5-dimethylphenyl boronic acid; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

trifluorormethanesulfonic acid; at 20 ℃; for 0.5h;

DOI:10.1002/chem.201804416

Reference yield: 56.0%

trifluorormethanesulfonic acid (1493-13-6) + para-xylene (106-42-3) → bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate (1000015-88-2)

Guidance literature:

para-xylene; With potassium peroxymonosulfate sulfate; sulfuric acid; iodine; In acetonitrile;

trifluorormethanesulfonic acid; In water; acetonitrile;

DOI:10.1002/adsc.202100426

Reference yield: 90.0%

bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate (1000015-88-2) + 2-Phenylphenol (90-43-7,287950-96-3) → 1-(3-methoxyphenoxy)-2,4-dimethylbenzene

Guidance literature:

2-Phenylphenol; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.25h;

bis(2,5-dimethylphenyl)iodonium trifluoromethanesulfonate; In tetrahydrofuran; at 40 ℃; for 0.333333h;

DOI:10.1002/chem.201201645

upstream raw materials:

trifluorormethanesulfonic acid

para-xylene

bis(acetyloxy)-(2,5-dimethylphenyl)-λ3-iodane

2,5-dimethylphenyl boronic acid

Downstream raw materials:

5,8-dimethyl-9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline

diethyl (2,5-dimethylphenyl)methylpropanedioate

2,5-dimethylphenyl-(4-methoxyphenyl)iodonium

2,5-dimethyldiphenyl sulfone