41018-54-6Relevant academic research and scientific papers
Copper-catalyzed diastereoselective arylation of tryptophan derivatives: Total synthesis of (+)-naseseazines A and B
Kieffer, Madeleine E.,Chuang, Kangway V.,Reisman, Sarah E.
supporting information, p. 5557 - 5560 (2013/05/22)
A copper-catalyzed arylation of tryptophan derivatives is reported. The reaction proceeds with high site-and diastereoselectivity to provide aryl pyrroloindoline products in one step from simple starting materials. The utility of this transformation is highlighted in the five-step syntheses of the natural products (+)-naseseazine A and B.
Straightforward syntheses of hypervalent iodine(III) reagents mediated by selectfluor
Ye, Chengfeng,Twamley, Brendan,Shreeve, Jean'ne M.
, p. 3961 - 3964 (2007/10/03)
(Chemical Equation Presented) Use of Selectfluor allows hypervalent iodine(III) species such as aryl iodine(III) difluoride, diacetate, and di(trifluoroacetate) and Koser's salt to be easily prepared. Aryl iodine(III) difluoride and diacetate can be synthesized from the corresponding arene and elemental iodine in one-pot procedures.
