mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Base Information

Chemical Name:mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)
CAS No.:138614-14-9
Molecular Formula:C₆₄H₅₉N₂O₄P₃Ru
Molecular Weight:1114.17
Hs Code.:

Synonyms:mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Suppliers and Price of mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

There total 2 articles about mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: (1,5-cyclooctadiene)(1,3,5-cyclooctatriene)ruthenium

: 105-56-6
ethyl 2-cyanoacetate

: 603-35-0
triphenylphosphine

: 138614-14-9
mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Guidance literature:: In tetrahydrofuran; (N2); addn. of NCCH2CO2Et to Ru complex and PPh3 in THF, stirring (room temp., 45 h); filtration, recrystn. (benzene/hexane);
DOI:10.1039/a902860i

Reference yield: 44.0%

: 27599-25-3,54083-06-6,19529-00-1
dihydridotetrakis(triphenylphosphine)ruthenium

: 105-56-6
ethyl 2-cyanoacetate

: 138614-14-9
mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

Guidance literature:: In tetrahydrofuran; byproducts: H2; room temp., 26 h;
DOI:10.1021/ja00155a008

Reference yield: 90.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 138614-14-9
mer-hydrido[[(ethoxycarbonyl)methyl]cyano](ethyl cyanoacetate)tris(triphenylphosphine)ruthenium(II)

: Ru₂Cl₄(NCCH₂COOC₂H₅)(P(C₆H₅)3)4*C₄H₈O

Guidance literature:: In tetrahydrofuran; byproducts: H2, ethyl cyanoacetate; stirring (room temp., 21 h), removal (vac.); recrystn. (THF/hexane);
DOI:10.1021/ja00155a008