dihydridotetrakis(triphenylphosphine)ruthenium

Base Information

• Chemical Name: dihydridotetrakis(triphenylphosphine)ruthenium
• CAS No.: 27599-25-3
• Molecular Formula: C₇₂H₆₂P₄Ru
• Molecular Weight: 1152.25
• Mol file: 27599-25-3.mol

Synonyms:

Chemical Property of dihydridotetrakis(triphenylphosphine)ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dihydridotetrakis(triphenylphosphine)ruthenium

There total 22 articles about dihydridotetrakis(triphenylphosphine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium tetrahydroborate (16940-66-2) + tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + triphenylphosphine (603-35-0) → dihydridotetrakis(triphenylphosphine)ruthenium (27599-25-3,54083-06-6,19529-00-1)

Guidance literature:

DOI:10.1021/ja961373w

Reference yield: 90.0%

sodium tetrahydroborate (16940-66-2) + ruthenium(III) chloride trihydrate (14898-67-0) + triphenylphosphine (603-35-0) → dihydridotetrakis(triphenylphosphine)ruthenium (27599-25-3,54083-06-6,19529-00-1)

Guidance literature:

DOI:10.1021/ja961373w

Reference yield: 60.0%

sodium tetrahydroborate (16940-66-2) + bis(aqua)chlorohydroxobis(triphenylphosphine)ruthenium(II) → dihydridotetrakis(triphenylphosphine)ruthenium (27599-25-3,54083-06-6,19529-00-1) + chlorohydridotris(triphenylphosphine)ruthenium(II) (55102-19-7,879374-40-0,879374-44-4,99944-74-8)

Guidance literature:

With triphenylphosphine; In water; toluene; Ar-atmosphere; stirring in toluene containing water (16 h); sepn. of toluene layer, volume reduction, pptn. on addn. of light petroleum; product mixt. not sepd., detd. by IR spectroscopy;

DOI:10.1039/DT9770001546

upstream raw materials:

chlorohydridotris(triphenylphosphine)ruthenium(II)

potassium tert-butylate

sodium tetrahydroborate

ruthenium(III) chloride trihydrate

Downstream raw materials:

hydridochlorotris(triphenylphosphine)ruthenium(II)

carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)

RuH(η5-OC6H5)(PPh3)

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾