1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

Base Information

Chemical Name:1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid
CAS No.:1410839-69-8
Molecular Formula:C₂₄H₂₈O₃Si
Molecular Weight:392.57
Hs Code.:

Synonyms:1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

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Chemical Property of 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

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Technology Process of 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

There total 2 articles about 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 62627-31-0
1-(hydroxymethyl)-2,5-cyclohexadiene-1-carboxylic acid

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1410839-69-8
1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 0.333333h;
DOI:10.1021/ol302908a

Reference yield:

: C₁₃H₁₈O₄

: 1410839-69-8
1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / tetrahydrofuran / 1.5 h / 0 - 20 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 0.33 h / 0 - 20 °C

With 1H-imidazole; sodium hydroxide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ol302908a

Reference yield: 93.0%

: 1410839-69-8
1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylic acid

: 1410839-87-0
(1R,5S,6S)-5-bromo-1-(((tert-butyldiphenylsilyl)oxy)methyl)-7-oxabicyclo[4.2.0]oct-2-en-8-one

: 1410839-88-1
5-bromo-1-(((tert-butyldiphenylsilyl)oxy)methyl)-7-oxabicyclo[4.2.0]oct-2-en-8-one

Guidance literature:: With 1,4-bis-(9-O-dihydroquinidinyl)phthalazine; N-Bromosuccinimide; In hexane; chloroform; at -40 ℃; for 1h; Reagent/catalyst; enantioselective reaction;
DOI:10.1021/ol302908a