(η5-Cp)FeBr(dppe)

Base Information

Chemical Name:(η5-Cp)FeBr(dppe)
CAS No.:32843-50-8
Molecular Formula:C₃₁H₂₉BrFeP₂
Molecular Weight:599.27
Hs Code.:

Synonyms:(η5-Cp)FeBr(dppe)

Suppliers and Price of (η5-Cp)FeBr(dppe)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (η5-Cp)FeBr(dppe)

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (η5-Cp)FeBr(dppe)

There total 4 articles about (η5-Cp)FeBr(dppe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.6%

: (C₅H₅)Fe(C₈H₁₂)^(1-)*Li(N(CH₃)2CH₂CH₂N(CH₃)2)⁽¹⁺⁾={(C₅H₅)Fe(C₈H₁₂)}{Li(N(CH₃)2C₂H₄N(CH₃)2)}

: 100-39-0
benzyl bromide

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 64827-29-8
C₅H₅Fe{(C₆H₅)2PCH₂}2(CH₂C₆H₅)

: 32843-50-8
(η5-Cp)FeBr(dppe)

Guidance literature:: In benzene-d6; under N2; to a soln. of the complex and the phosphine in benzene-d6 was added benzyl bromide in benzene-d6; slow evapn.;
DOI:10.1021/ja00086a022

Reference yield: 68.0%

: [FeBr₂(bis(diphenylphosphino)ethane)]n

: potassium cyclopentadiene

: 32843-50-8
(η5-Cp)FeBr(dppe)

Guidance literature:: In toluene; at -78 - 20 ℃; for 18h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/c5dt00704f

Reference yield: 43.0%

: 41536-18-9
{1,2-bis(diphenylphosphino)ethane}dichloroiron

: 17306-10-4
cyclopentadienylmagnesium bromide

: 102-54-5,55404-68-7
ferrocene

: 32843-50-8
(η5-Cp)FeBr(dppe)

Guidance literature:: In tetrahydrofuran; byproducts: MgCl2; dropwise addn. of CpMgCl in THF to (Ph2P(CH2)2PPh2)FeCl2 in THF under Ar at 20°C; 24 h at 20°C;; evapn. under vac.; extn. with toluene at 50°C several times; filtration; crystn. from the filtrate on cooling at -20°C for 10 d; elem. anal.;;