(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

Base Information

Chemical Name:(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane
CAS No.:380605-87-8
Molecular Formula:C₂₇H₄₆O₄Si
Molecular Weight:462.745
Hs Code.:

Synonyms:(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

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Chemical Property of (2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

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Technology Process of (2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

There total 4 articles about (2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 380605-86-7
(-)-(2R,3S,5Z)-2-(4-methoxybenzyloxy)-6,10-dimethylundeca-5,10-dien-3-ol

: 380605-87-8
(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 6h;
DOI:10.1021/jo048742o

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 380605-87-8
(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 86 percent / sodium hydride; tetrabutylammonium iodide / tetrahydrofuran / 6 h / 0 °C

2.1: copper(I) bromide-dimethyl sulfide / diethyl ether; various solvent(s) / 2 h / -45 °C

2.2: 1-hexyne; n-butyllithium; HMPA / diethyl ether; various solvent(s); hexane / 5 h / -78 - -23 °C

2.3: 75 percent / diethyl ether; various solvent(s); hexane / 17 h / -78 - -25 °C

3.1: 92 percent / DIPEA / CH₂Cl₂ / 6 h / 20 °C

With copper(I) bromide dimethylsulfide complex; tetra-(n-butyl)ammonium iodide; sodium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; 2.2: Normant reaction / 2.3: Normant reaction;
DOI:10.1021/jo048742o

Reference yield:

: 380605-85-6
(2S,3R)-3-(4-methoxybenzyloxy)-1,2-epoxybutane

: 380605-87-8
(2-{1-[1-(4-methoxy-benzyloxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyloxymethoxy}-ethyl)-trimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: copper(I) bromide-dimethyl sulfide / diethyl ether; various solvent(s) / 2 h / -45 °C

1.2: 1-hexyne; n-butyllithium; HMPA / diethyl ether; various solvent(s); hexane / 5 h / -78 - -23 °C

1.3: 75 percent / diethyl ether; various solvent(s); hexane / 17 h / -78 - -25 °C

2.1: 92 percent / DIPEA / CH₂Cl₂ / 6 h / 20 °C

With copper(I) bromide dimethylsulfide complex; N-ethyl-N,N-diisopropylamine; In diethyl ether; dichloromethane; 1.2: Normant reaction / 1.3: Normant reaction;
DOI:10.1021/jo048742o