methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

Base Information

Chemical Name:methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside
CAS No.:939051-48-6
Molecular Formula:C₄₀H₅₂O₁₀
Molecular Weight:692.847
Hs Code.:

methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

Synonyms:methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

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Chemical Property of methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

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Technology Process of methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

There total 11 articles about methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 939050-75-6
methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-benzylsulfonyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

: 939051-48-6
methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / NaNH₂ / dimethylformamide / 1 h / 70 °C / microwave irradiation

2: I₂; Et₃SiH / toluene / 2 h / -94 °C

3: 76 percent / NaNH₂ / dimethylformamide / 1 h / 70 °C / microwave irradiation

With triethylsilane; iodine; sodium amide; In N,N-dimethyl-formamide; toluene;
DOI:10.1002/anie.200604031

Reference yield:

: O-(3-O-benzyl-4-O-benzylsulfonyl-2,6-dideoxy-D-arabino-hexopyranosyl) trichloroacetimidate

: 939051-48-6
methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: I₂; Et₃SiH / toluene / 2 h / -94 °C

2: 76 percent / NaNH₂ / dimethylformamide / 1 h / 70 °C / microwave irradiation

With triethylsilane; iodine; sodium amide; In N,N-dimethyl-formamide; toluene;
DOI:10.1002/anie.200604031

Reference yield:

: 18546-25-3
6-O-p-tolylsulfonyl-3,4-di-O-acetyl-D-glucal

: 939051-48-6
methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-(3-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 9 steps

1.1: NaBr; NaHCO₃ / dimethylformamide / 12 h / 65 °C

2.1: 13.0 g / Bu₃SnH; AIBN / toluene / 1.5 h / 110 °C

3.1: 80 percent / LiBr; Dowex(R) 50Wx₄ / acetonitrile / 3 h / 20 °C

4.1: 95 percent / NaOMe; MeOH / 2 h / 20 °C

5.1: Bu₂SnO / toluene / 5 h / Heating

5.2: 85 percent / Bu₄NI / toluene / 12 h / 100 °C

6.1: I₂; Et₃SiH / toluene / 1.5 h / -94 °C

7.1: 84 percent / NaNH₂ / dimethylformamide / 1 h / 70 °C / microwave irradiation

8.1: I₂; Et₃SiH / toluene / 2 h / -94 °C

9.1: 76 percent / NaNH₂ / dimethylformamide / 1 h / 70 °C / microwave irradiation

With methanol; triethylsilane; 2,2'-azobis(isobutyronitrile); Dowex(R) 50WX₄; iodine; tri-n-butyl-tin hydride; sodium methylate; di(n-butyl)tin oxide; sodium hydrogencarbonate; sodium amide; sodium bromide; lithium bromide; In N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1002/anie.200604031