methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

Base Information

Chemical Name:methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester
CAS No.:849122-70-9
Molecular Formula:C₂₀H₃₆O₅S
Molecular Weight:388.569
Hs Code.:

Synonyms:methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

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Chemical Property of methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

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Technology Process of methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

There total 5 articles about methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 849122-69-6
{(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methanol

: 124-63-0
methanesulfonyl chloride

: 849122-70-9
methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 15h;
DOI:10.1016/j.tet.2004.12.039

Reference yield:

: (1R,2R,6R)-6-Isopropyl-2-((2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl)-3-methyl-cyclohex-3-enecarbaldehyde

: 849122-70-9
methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 505 mg / NaBH₄ / ethanol / 0.33 h / 20 °C

2: 100 percent / Et₃N / CH₂Cl₂ / 15 h / 20 °C

With sodium tetrahydroborate; triethylamine; In ethanol; dichloromethane;
DOI:10.1016/j.tet.2004.12.039

Reference yield:

: 849122-67-4
(2S,3R)-1-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-3-methyl-pent-4-en-2-ol

: 849122-70-9
methanesulfonic acid {(1R,2R,6R)-6-isopropyl-2-[(2S,3R)-2-methoxymethoxy-3-methyl-pent-4-enyl]-3-methyl-cyclohex-3-enyl}-methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 82 percent / DIPEA; TBAI / CH₂Cl₂ / 15 h / 20 °C

2: LiBF₄ / acetonitrile; H₂O / 1 h / 20 °C

3: 505 mg / NaBH₄ / ethanol / 0.33 h / 20 °C

4: 100 percent / Et₃N / CH₂Cl₂ / 15 h / 20 °C

With sodium tetrahydroborate; lithium tetrafluoroborate; tetra-(n-butyl)ammonium iodide; triethylamine; N-ethyl-N,N-diisopropylamine; In ethanol; dichloromethane; water; acetonitrile;
DOI:10.1016/j.tet.2004.12.039