benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose

Base Information

• Chemical Name: benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose
• CAS No.: 81102-08-1
• Molecular Formula: C₂₀H₂₁IN₄O₄
• Molecular Weight: 508.316
• Mol file: 81102-08-1.mol

Synonyms:benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose

Chemical Property of benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose

There total 3 articles about benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl 2,3-anhydro-4-azido-4-deoxy-β-L-ribopyranoside (59495-15-7) → benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose (81102-08-1)

Guidance literature:

Multi-step reaction with 3 steps

2: sodium hydrogencarbonate / 3 h / Ambient temperature

3: sodium iodide, sodium acetate, acetic acid / acetone / 5 h / Heating

With sodium acetate; sodium hydrogencarbonate; acetic acid; sodium iodide; In acetone;

DOI:10.1016/S0008-6215(00)80975-1

Reference yield:

benzyl 4-azido-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside (81102-02-5) → benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose (81102-08-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydrogencarbonate / 3 h / Ambient temperature

2: sodium iodide, sodium acetate, acetic acid / acetone / 5 h / Heating

With sodium acetate; sodium hydrogencarbonate; acetic acid; sodium iodide; In acetone;

DOI:10.1016/S0008-6215(00)80975-1

Reference yield:

benzyl 4-azido-N-benzoyloxycarbonyl-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside (81102-04-7) → benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose (81102-08-1) + benzyl 4-azido-3-(benzyloxycarbonyl)amino-2,3,4-trideoxy-2-iodo-β-L-xylopyranoside

Guidance literature:

With sodium acetate; acetic acid; sodium iodide; In acetone; for 5h; Yield given. Yields of byproduct given; Heating;

DOI:10.1016/S0008-6215(00)80975-1

upstream raw materials:

benzyl 4-azido-N-benzoyloxycarbonyl-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside

benzyl 2,3-anhydro-4-azido-4-deoxy-β-L-ribopyranoside

benzyl 4-azido-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside