59495-15-7

Upstream product

• 71204-46-1 benzyl 2,3-anhydro-4-O-(trifluoromethylsulfonyl)-α-D-lyxopyranoside 
• 71204-43-8 benzyl 2,3-anhydro-α-D-lyxopyranoside 

Downstream Products

• 81102-08-1 benzyl 4-azido-2-(benzyloxycarbonylamino)-2,3,4-trideoxy-3-iodo-β-L-arabinopyranose 
• 81102-04-7 benzyl 4-azido-N-benzoyloxycarbonyl-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside 
• 81102-10-5 N-((2S,3S,4R,5R)-5-Azido-2-benzyloxy-3-iodo-tetrahydro-pyran-4-yl)-acetamide 
• 81102-03-6 benzyl N-acetyl-4-azido-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside 
• 81102-09-2 (2S,3S,4R,5R)-5-Azido-2-benzyloxy-3-iodo-tetrahydro-pyran-4-ylamine 
• 65518-85-6 benzyl-2,3-anhydro-4-amino-4-desoxy-β-L-ribopyranoside 
• 81102-02-5 benzyl 4-azido-2,3,4-trideoxy-2,3-epimino-β-L-lyxopyranoside 
• 59495-17-9 benzyl 2-amino-4-azido-2,4-dideoxy-β-L-arabinopyranoside 

Relevant academic research and scientific papers

C-4-Triflate Displacement by Azide in 2,3-Anhydro Sugars; a New Way to 4-Amino-4-deoxy Sugars

Displacement of the triflyl by the azido group in benzyl-2,3-anhydro-4-triflyl-α-D-pyranosides 4-6 gives with inversion the benzyl-2,3-anhydro-4-azido-4-deoxypyranosides 7-9.The triflyl group turns out to be a reactive leaving group which can be replaced