carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate

Base Information

• Chemical Name: carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate
• CAS No.: 112084-01-2
• Molecular Formula: CF₃O₃S*C₃₉H₃₆IrOP₂
• Molecular Weight: 923.952
• Mol file: 112084-01-2.mol

Synonyms:carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate

Chemical Property of carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate

There total 1 articles about carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(P(C6H5)3)2Ir(CO)(CH3)2I + silver trifluoromethanesulfonate (2923-28-6) → carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate (112084-01-2)

Guidance literature:

In tetrahydrofuran; under N2 or Ar, to suspn. of IrMe2(CO)I(PPh3)2 in THF addn. of CF3SO3Ag(1.05 equivs.) with stirring, stirred for 10 min; filtered, addn. of hexanes, solid collected via suction filtration, washed with hexanes;

DOI:10.1016/0022-328X(87)80372-8

Reference yield: 92.0%

carbonyldimethylbis(triphenylphosphine)iridium(III) trifluoromethanesulphonate (112084-01-2) → cis-dimethyl-cis-dicarbonyl-trans-bis(triphenylphosphine)iridium(III) trifluoromethanesulphonate (112100-76-2)

Guidance literature:

With CO; In tetrahydrofuran; soln. of (IrMe2(CO)(PPh3)2)(CF3SO3) in THF stirred under CO for 30 min; hexanes are added, ppt. collected by suction filtration; elem. anal.;

DOI:10.1016/0022-328X(87)80372-8

upstream raw materials:

silver trifluoromethanesulfonate

Downstream raw materials:

cis-dimethyl-cis-dicarbonyl-trans-bis(triphenylphosphine)iridium(III) trifluoromethanesulphonate