2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride

Base Information

• Chemical Name: 2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride
• CAS No.: 622847-64-7
• Molecular Formula: C₂₃H₁₇Cl₂CoF₆N₃
• Molecular Weight: 579.298
• Mol file: 622847-64-7.mol

Synonyms:2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride

Chemical Property of 2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride

Chemical Property:

Purity/Quality:

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Technology Process of 2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride

There total 1 articles about 2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

cobalt(II) chloride dihydrate + N,N'-(1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene))bis(2-(trifluoromethyl)aniline) (500117-04-4) → 2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride (622847-64-7)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2019.02.002

Reference yield:

2,6-bis[1-(2-trifluoromethylphenylimino)ethyl]pyridine cobalt(II) chloride (622847-64-7) + trimethylaluminum (75-24-1) + trityl tetrakis(pentafluorophenyl)borate → [(NC5H3(C(Me)NC6H4CF3)2)Co(II)(μ-Me)2AlMe2][B(C6F5)4]

Guidance literature:

In ⁽²⁾H₈-toluene; using sealed high vac. systems; in NMR tube; Co complex cooled in liq. N2 (77 K); toluene-d8, AlMe3 (10 equiv.) and (CPh3)B(C6F5)4 (2 equiv.) added; reacted at -40°C for 30 min; not isolated; monitored by (1)H NMR spectra;

DOI:10.1021/om900490b

upstream raw materials:

N,N'-(1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene))bis(2-(trifluoromethyl)aniline)