9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole

Base Information

• Chemical Name: 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole
• CAS No.: 1185863-81-3
• Molecular Formula: C₄₁H₂₃F₁₂N
• Molecular Weight: 757.621
• Mol file: 1185863-81-3.mol

Synonyms:9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole

Chemical Property of 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole

There total 2 articles about 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1-methylindole (603-76-9) + 1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole (1185863-81-3)

Guidance literature:

With 2,6-dimethylbenzoic acid; palladium diacetate; silver carbonate; In 1,3,5-trimethyl-benzene; at 120 ℃; for 10h; regioselective reaction; Inert atmosphere;

DOI:10.1021/jo9016698

Reference yield: 46.0%

1-methyl-3-indolecarboxylic acid (32387-21-6) + 1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → (Z)-1-(1-methylindole-3-carboxy)-1,2-bis[4-(trifluoromethyl)phenyl]ethene + 9-methyl-1,2,3,4-tetrakis(4-trifluoromethylphenyl)-9H-carbazole (1185863-81-3)

Guidance literature:

With lithium acetate; copper diacetate; palladium diacetate; In N,N-dimethyl acetamide; at 120 ℃; for 9h; regioselective reaction; Molecular sieve; Inert atmosphere;

DOI:10.1021/jo9016698

upstream raw materials:

1-methylindole

1,2-bis(4-(trifluoromethyl)phenyl)ethyne

1-methyl-3-indolecarboxylic acid