tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane

Base Information

• Chemical Name: tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane
• CAS No.: 256519-24-1
• Molecular Formula: C₁₄H₂₆OSi
• Molecular Weight: 238.445
• Mol file: 256519-24-1.mol

Synonyms:tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane

Chemical Property of tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane

There total 2 articles about tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4,4-dimethylcyclohexenone (1073-13-8) + tert-butyldimethylsilyl chloride (18162-48-6) → tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane (256519-24-1)

Guidance literature:

4,4-dimethylcyclohexenone; With potassium hexamethylsilazane; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; at -78 - 20 ℃; for 2.25h; Inert atmosphere;

DOI:10.1021/acs.orglett.0c03005

Reference yield: 95.0%

4,4-dimethylcyclohexenone (1073-13-8) + t-butyldimethylsiyl triflate (69739-34-0) → tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane (256519-24-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 0.25h;

DOI:10.1016/S0040-4020(99)00982-5

Reference yield: 66.0%

tert-butyl((4,4-dimethylcyclohexa-1,5-dien-1-yl)oxy)dimethylsilane (256519-24-1) → 2-(tert-butyldimethylsiloxy)-4,4-dimethyl-5-cyclohexenone (97997-19-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid;

DOI:10.1016/0040-4039(95)01192-K

upstream raw materials:

4,4-dimethylcyclohexenone

tert-butyldimethylsilyl chloride

t-butyldimethylsiyl triflate

Downstream raw materials:

2-(tert-butyldimethylsiloxy)-4,4-dimethyl-5-cyclohexenone