2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

Base Information

Chemical Name:2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline
CAS No.:369390-66-9
Molecular Formula:C₂₆H₂₆N₂Si
Molecular Weight:394.591
Hs Code.:

Synonyms:2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

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Chemical Property of 2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

Chemical Property:

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Technology Process of 2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

There total 4 articles about 2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 369390-80-7
2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-1,2-dihydro-[1,10]phenanthroline

: 369390-66-9
2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

Guidance literature:: With manganese(IV) oxide; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1055/s-2001-16093

Reference yield:

: 66127-01-3
3-bromophenanthroline

: 369390-66-9
2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 3 steps

1.1: 92 percent / CuI; Et₃N / PdCl₂(PPh₃)2 / benzene / 24 h / 80 - 90 °C

2.1: n-BuLi / diethyl ether; hexane / 14 h / 0 °C

2.2: 69 percent / diethyl ether; hexane / 22 h / 20 °C

3.1: 90 percent / MnO₂ / CH₂Cl₂ / 2 h / 20 °C

With manganese(IV) oxide; copper(l) iodide; n-butyllithium; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In diethyl ether; hexane; dichloromethane; benzene; 1.1: Sonogashira coupling;
DOI:10.1055/s-2001-16093

Reference yield:

: 1066-54-2
trimethylsilylacetylene

: 369390-66-9
2-(2,4,6-Trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 3 steps

1.1: 92 percent / CuI; Et₃N / PdCl₂(PPh₃)2 / benzene / 24 h / 80 - 90 °C

2.1: n-BuLi / diethyl ether; hexane / 14 h / 0 °C

2.2: 69 percent / diethyl ether; hexane / 22 h / 20 °C

3.1: 90 percent / MnO₂ / CH₂Cl₂ / 2 h / 20 °C

With manganese(IV) oxide; copper(l) iodide; n-butyllithium; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In diethyl ether; hexane; dichloromethane; benzene; 1.1: Sonogashira coupling;
DOI:10.1055/s-2001-16093