methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

Base Information

Chemical Name:methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate
CAS No.:118607-99-1
Molecular Formula:C₁₈H₂₅IO₈S₂
Molecular Weight:560.428
Hs Code.:

Synonyms:methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

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Technology Process of methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

There total 10 articles about methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 118607-98-0
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

: 118607-99-1
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

Guidance literature:: With sodium iodide; In acetone; at 50 ℃; for 16h;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 1071-73-4
5-Hydroxy-2-pentanone

: 118607-99-1
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 8 steps

1: 85 percent / imidazole / dimethylformamide / 24 h / 70 °C

2: 17.25 g / NaH / tetrahydrofuran; hexane; diethyl ether / 40 h / Ambient temperature

3: 96 percent / DIBAL / CH₂Cl₂ / -78 deg C, 1 h, then 0 deg C

4: CBr₄, Ph₃P / CH₂Cl₂ / 1 h / -78 °C

5: 3.10 g / toluene / 12 h / Heating

6: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran / 4 h

7: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h

8: 97 percent / NaI / acetone / 16 h / 50 °C

With 1H-imidazole; carbon tetrabromide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; triphenylphosphine; sodium iodide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 86864-59-7
5-((tert-butyldimethylsilyl)oxy)pentan-2-one

: 118607-99-1
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(6-iodo-3-methyl)-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 7 steps

1: 17.25 g / NaH / tetrahydrofuran; hexane; diethyl ether / 40 h / Ambient temperature

2: 96 percent / DIBAL / CH₂Cl₂ / -78 deg C, 1 h, then 0 deg C

3: CBr₄, Ph₃P / CH₂Cl₂ / 1 h / -78 °C

4: 3.10 g / toluene / 12 h / Heating

5: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran / 4 h

6: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h

7: 97 percent / NaI / acetone / 16 h / 50 °C

With carbon tetrabromide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; triphenylphosphine; sodium iodide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetone; toluene;
DOI:10.1016/S0040-4020(01)85090-0