triphenylphosphine p-toluenethiolate gold(I) complex

Base Information

• Chemical Name: triphenylphosphine p-toluenethiolate gold(I) complex
• CAS No.: 121860-53-5
• Molecular Formula: C₂₅H₂₂AuPS
• Molecular Weight: 582.456
• Mol file: 121860-53-5.mol

Synonyms:triphenylphosphine p-toluenethiolate gold(I) complex

Chemical Property of triphenylphosphine p-toluenethiolate gold(I) complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylphosphine p-toluenethiolate gold(I) complex

There total 5 articles about triphenylphosphine p-toluenethiolate gold(I) complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(C6H3NO2)NCOCH2NC(C6H5)AuP(C6H5)3 (128493-73-2) + para-thiocresol (106-45-6) → triphenylphosphine p-toluenethiolate gold(I) complex (121860-53-5) + nitrazepam (146-22-5)

Guidance literature:

In methanol; stirring of a soln. of thiol and Au-compd. in MeOH for 1 h at room temp.; evapn. to dryness, dissolving of residue with diethyl ether gives ligand(IR, mp), evapn. of ether soln. to dryness, dissolving of residue in CHCl3, addn. of hexane, elem. anal.;

DOI:10.1016/S0020-1693(00)88014-7

Reference yield:

(triphenylphosphine)gold(I) chloride (14243-64-2) → triphenylphosphine p-toluenethiolate gold(I) complex (121860-53-5)

Guidance literature:

Multi-step reaction with 2 steps

1: KOH / water; tetrahydrofuran

2: chloroform

With KOH; In tetrahydrofuran; chloroform; water;

DOI:10.1246/bcsj.62.1078

Reference yield:

(triphenylphosphine)gold(I) chloride (14243-64-2) + ethanolamine (141-43-5) + para-thiocresol (106-45-6) → triphenylphosphine p-toluenethiolate gold(I) complex (121860-53-5)

Guidance literature:

In ethanol; dichloromethane; N2; addn. of a solution of the ligand and ethanolamine to a solution of the AuCl-complex in CH2Cl2; 30 min stirring;; solvent concentration; cooling on an ice bath; precipitation; filtration; recrystn. from CH2Cl2/hexanes or CH2Cl2/Et2O; elem. anal.;;

upstream raw materials:

(triphenylphosphine)gold(I) chloride

ethanolamine

para-thiocresol

{5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I)

Downstream raw materials:

NO₂C₆H₄SAuP(C₆H₅)3

di(p-tolyl) disulfide

4-nitrophenyl p-tolyl disulfide