N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine

Base Information

• Chemical Name: N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine
• CAS No.: 461392-23-4
• Molecular Formula: C₁₅H₂₃N
• Molecular Weight: 217.354
• Mol file: 461392-23-4.mol

Synonyms:N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine

Chemical Property of N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine

There total 2 articles about N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

4-tert-Butylbenzaldehyde (939-97-9) + tert-butylamine (75-64-9) → N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine (461392-23-4)

Guidance literature:

With titanium tetrachloride; In diethyl ether; toluene; at 0 ℃; for 0.25h; Glovebox; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201600716

Reference yield:

tert-butylisonitrile (119072-55-8,7188-38-7) + 1-tert-butyl-4-iodobenzene (35779-04-5) → N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine (461392-23-4)

Guidance literature:

With sodium formate; palladium diacetate; 1,2-bis-(diphenylphosphino)ethane; In dimethyl sulfoxide; Inert atmosphere; Sealed tube;

DOI:10.1039/c4ra16388e

Reference yield: 97.0%

N-[4-(1,1-dimethylethyl)benzylidene]-1,1-dimethylethylamine (461392-23-4) → N-(4-tert-butylbenzyl)-tert-butylamine (125640-90-6)

Guidance literature:

With hydrogen; diisobutylaluminium hydride; In toluene; at 100 ℃; for 24h; under 77525.2 Torr; Reagent/catalyst;

DOI:10.1039/c3cc47889k

upstream raw materials:

4-tert-Butylbenzaldehyde

tert-butylamine

tert-butylisonitrile

1-tert-butyl-4-iodobenzene

Downstream raw materials:

4-tert-butyl benzonitrile

N-(4-tert-butylbenzyl)-tert-butylamine

4-tert-Butylbenzaldehyde