{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane

Base Information

• Chemical Name: {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane
• CAS No.: 143953-71-3
• Molecular Formula: C₄₂H₈₄OSSi₆Sn
• Molecular Weight: 924.417
• Mol file: 143953-71-3.mol

Synonyms:{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane

Chemical Property of {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane

There total 6 articles about {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-(2,4,6-triisopropylphenyl)-4-{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-1,2,3,4,5-tetrathiastannolane (143953-70-2) → 2,4-bis{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-2,4-bis(2,4,6-triisopropylphenyl)-1,3,2,4-dithiadistannetane (148843-48-5,148843-50-9) + {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane (143953-71-3)

Guidance literature:

With triphenylphosphine; In toluene; addn. of PPh3 to the stannolane in toluene at room temp. under Ar, refluxed for 10 h; evapd., chromy., recrystn. (ethanol/CHCl3), mixt. of cis-trans-isomer 1:1, elem. anal.;

DOI:10.1021/om00031a030

Reference yield: 56.0%

4-(2,4,6-triisopropylphenyl)-4-{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-1,2,3,4,5-tetrathiastannolane (143953-70-2) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 2-{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1,2,4-thiastannacyclohex-4-ene (148843-49-6) + {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane (143953-71-3)

Guidance literature:

With triphenylphosphine; In hexane; refluxed for 10 h under Ar; evapd., chromy., recrystn. (ethanol/CHCl3), elem. anal.;

DOI:10.1021/om00031a030

Reference yield: 54.0%

4-(2,4,6-triisopropylphenyl)-4-{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-1,2,3,4,5-tetrathiastannolane (143953-70-2) → trans-2,4-bis{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-2,4-bis(2,4,6-triisopropylphenyl)-1,3,2,4-dithiadistannetane (148843-48-5,148843-50-9) + {2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}hydroxy(2,4,6-triisopropylphenyl)mercaptostannane (143953-71-3)

Guidance literature:

With triphenylphosphine; In hexane; addn. of PPh3 to the stannolane in hexane at room temp. under Ar, stirred for 10 h; evapd., chromy., recrystn. (ethanol/CHCl3), elem. anal.;

DOI:10.1021/om00031a030

upstream raw materials:

4-(2,4,6-triisopropylphenyl)-4-{2,4,6-tris(bis(trimethylsilyl)methyl)phenyl}-1,2,3,4,5-tetrathiastannolane

2,3-dimethyl-buta-1,3-diene

styrene oxide