4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine

Base Information

• Chemical Name: 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine
• CAS No.: 1226052-93-2
• Molecular Formula: C₂₃H₁₆N₄
• Molecular Weight: 348.407
• Mol file: 1226052-93-2.mol

Synonyms:4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine

Chemical Property of 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine

There total 1 articles about 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

sodium cyanide (773837-37-9) + 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine (89972-78-1) → 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine (1226052-93-2)

Guidance literature:

In N,N-dimethyl-formamide; at 20 ℃; for 10h;

DOI:10.1021/ic100138s

Reference yield: 40.0%

ammonium hexafluorophosphate + [(H2(2,6-bis(benzimidazole-2-yl))pyridine)RuCl3] (243982-73-2) + 4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine (1226052-93-2) → [(2,6-bis(benzimidazole-2-yl)pyridine)Ru(4'-(p-cyanomethylphenyl)-2,2':6',2''-terpyridine)](PF6)2

Guidance literature:

In water; ethylene glycol; (N2); terpyridine was added to suspn. of ruthenium complex in ethylene glycol at 100°C, heated at 200°C for 24 h, cooled, aq. NH4PF6 was added; filtered, washed with water, Et2O, dried in vac., column chromy. (silica, MeCN/10% aq. KNO3, 10:1), treated with NH4PF6, crystd. from MeCN/MeOH (1:1) in the presence of 10E-4 aq. HPF6, elem. anal.;

DOI:10.1021/ic100138s

upstream raw materials:

sodium cyanide

4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine