9-SC₆H₅-1.7-C₂B₁₀H₁₁

Base Information

Chemical Name:9-SC₆H₅-1.7-C₂B₁₀H₁₁
CAS No.:90311-23-2
Molecular Formula:C₈H₁₆B₁₀S
Molecular Weight:252.391
Hs Code.:

9-SC<sub>6</sub>H<sub>5</sub>-1.7-C<sub>2</sub>B<sub>10</sub>H<sub>11</sub>

Synonyms:9-SC₆H₅-1.7-C₂B₁₀H₁₁

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Chemical Property of 9-SC₆H₅-1.7-C₂B₁₀H₁₁

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Technology Process of 9-SC₆H₅-1.7-C₂B₁₀H₁₁

There total 4 articles about 9-SC₆H₅-1.7-C₂B₁₀H₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 90311-18-5
9-m-carboranyl sulfenylchloride

: 100-58-3
phenylmagnesium bromide

: 64493-44-3
9-(mercapto)-1,7-dicarba-closo-dodecaborane⁽¹²⁾

: 90311-23-2
9-SC₆H₅-1.7-C₂B₁₀H₁₁

Guidance literature:: With hydrogenchloride; In diethyl ether; byproducts: PhCl; inert atmosphere; addn. of carboranyl compound in ether to soln. of PhMgBr (15°C), refluxing (2 h), addn. of aq. HCl; sepn. of org. layer, washing (aq. alkali, water), drying (over MgSO4), removal of solvent, chromy. (silica gel, hexane); sepn. of m-C2H2B10H9)2S2 from alkaline soln.;
DOI:10.1007/BF00951070

Reference yield: 66.0%

: 90311-18-5
9-m-carboranyl sulfenylchloride

: 100-58-3
phenylmagnesium bromide

: 90311-23-2
9-SC₆H₅-1.7-C₂B₁₀H₁₁

Guidance literature:: In diethyl ether; byproducts: m-H2C2B10H9SH; inert atmosphere, to an ether soln. of PhMgBr at 15 ° C was added an ether soln. of carborane, mixture refluxed for 2h; decompn. with dild. HCl, ether layer septd., washed with alkaline soln. to remove thiol, washed with water, dried, solvent distd. off, chromy. (silica gel, hexane), thiol isolated from alkaline soln., elem. anal. for sulfide;

Reference yield: 48.0%

: 90311-18-5
9-m-carboranyl sulfenylchloride

: 90311-23-2
9-SC₆H₅-1.7-C₂B₁₀H₁₁

Guidance literature:: With iron(III) chloride; benzene; In benzene; inert atmosphere; refluxing (10 h); cooling, addn. of water and ether, sepn. of org. layer, drying (over MgSO4), removal of solvent, chromy. (silica gel, hexane); elem. anal.;
DOI:10.1007/BF00951070