(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

Base Information

Chemical Name:(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene
CAS No.:945903-63-9
Molecular Formula:C₃₁H₃₈OSi
Molecular Weight:454.728
Hs Code.:

Synonyms:(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

Suppliers and Price of (1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

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Technology Process of (1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

There total 6 articles about (1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 945903-62-8
(1E,4S,5S)-5-tert-butyldiphenylsilyloxy-1-iodo-4-methyl-hex-1-ene

: 6783-05-7
trans-2-phenylvinylboronic acid

: 945903-63-9
(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

Guidance literature:: With potassium hydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 50 ℃; for 4h;
DOI:10.1016/j.tet.2007.04.061

Reference yield:

: 945903-59-3
(3S,4S)-4-tert-butyldiphenylsilyloxy-3-methyl-pent-1-ene

: 945903-63-9
(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

Guidance literature:: Multi-step reaction with 4 steps

1.1: BH₃*SMe₂ / hexane; tetrahydrofuran / 26 h / 20 °C

1.2: aq. NaOH; H₂O₂ / hexane; tetrahydrofuran / 20 °C

2.1: pyridinium dichromate / CH₂Cl₂ / 3 h / 20 °C

3.1: CrCl₂ / tetrahydrofuran; dioxane / 24 h / 0 °C

4.1: aq. KOH / Pd(PPh₃)4 / tetrahydrofuran / 4 h / 50 °C

With chromium dichloride; potassium hydroxide; dipyridinium dichromate; dimethylsulfide borane complex; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; hexane; dichloromethane; 4.1: Suzuki coupling;
DOI:10.1016/j.tet.2007.04.061

Reference yield:

: 945903-61-7
(3S,4S)-4-tert-butyldiphenylsilyloxy-3-methyl-pentan-1-al

: 945903-63-9
(1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene

Guidance literature:: Multi-step reaction with 2 steps

1: CrCl₂ / tetrahydrofuran; dioxane / 24 h / 0 °C

2: aq. KOH / Pd(PPh₃)4 / tetrahydrofuran / 4 h / 50 °C

With chromium dichloride; potassium hydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; 2: Suzuki coupling;
DOI:10.1016/j.tet.2007.04.061