1,2-Epoxypentane

Base Information

• Chemical Name: 1,2-Epoxypentane
• CAS No.: 1003-14-1
• Deprecated CAS: 138128-26-4
• Molecular Formula: C5H10 O
• Molecular Weight: 86.1338
• Hs Code.: 2910900090
• European Community (EC) Number: 213-701-3,304-797-9
• NSC Number: 46349
• DSSTox Substance ID: DTXSID40883637
• Nikkaji Number: J65.579A
• Mol file: 1003-14-1.mol

Synonyms:1,2-Epoxypentane;1003-14-1;PROPYLOXIRANE;2-Propyloxirane;1-Pentene oxide;Oxirane, propyl-;Propylethylene oxide;Pentene 1,2-oxide;Oxirane, 2-propyl-;Pentane, 1,2-epoxy-;Pentylene oxide;1,2-Pentylene Oxide;EINECS 213-701-3;NSC 46349;BRN 0102422;EC 213-701-3;5-17-01-00087 (Beilstein Handbook Reference);Pentane,2-epoxy-;2-Propyloxirane #;1,2-epoxy-pentane;Pentene-1,2-oxide;pentene - 1,2-oxide;1,2-Epoxypentane, 98%;DTXSID40883637;NSC46349;EINECS 304-797-9;MFCD00192124;NSC-46349;AKOS009156937;LS-101723;E0822;FT-0606454;FT-0773186;D90574;EN300-119384;J-640020;J-800021;(s)-(-)-|A,|A-diphenyl-2-pyrrolidinemethanoltrimethylsilylether;94279-52-4

Chemical Property of 1,2-Epoxypentane

Chemical Property:

• Vapor Pressure: 57mmHg at 25°C
• Refractive Index: n20/D 1.396(lit.)
• Boiling Point: 89-90 °C750 mm Hg(lit.)
• Flash Point: 10 °F
• PSA: 12.53000
• Density: 0.83 g/mL at 25 °C(lit.)
• LogP: 1.18530
• Storage Temp.: 2-8°C
• Water Solubility.: 23g/L at 20℃
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 86.073164938
• Heavy Atom Count: 6
• Complexity: 43.2

Purity/Quality:

99.9% ^*data from raw suppliers

1,2-Epoxypentane >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11-40-20/21/22
• Safety Statements: 16-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC1CO1

Technology Process of 1,2-Epoxypentane

There total 11 articles about 1,2-Epoxypentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-penten (109-67-1) → 2-pentyloxirane (1003-14-1)

Guidance literature:

With peracetic acid; C₈₀H₈₄Mn₂N₈O₄*4ClO₄^(1-); In acetonitrile; at 0 ℃; for 0.5h;

DOI:10.1039/c0dt00953a

Reference yield:

1-penten (109-67-1) → 2-pentyloxirane (1003-14-1) + Z-piperylene (1574-41-0,17410-45-6,25212-15-1,64940-84-7) + 1-methylbuta-1,3-diene (2004-70-8,17410-45-6,25212-15-1,64940-84-7) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + ethene (74-85-1) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2)

Guidance literature:

With (per)acetylperoxyboric acid; hydrogen; oxygen; at 480 ℃; Mechanism;

DOI:10.1039/f19807602396

Reference yield:

1-bromopentan-2-ol (26818-03-1) → 2-pentyloxirane (1003-14-1)

Guidance literature:

With sodium hydroxide; under 30 Torr;

upstream raw materials:

1-penten

1-bromopentan-2-ol

1-iodo-pentan-2-ol

Rh(III)(tetra(p-sulfonatophenyl)porphyrinato)(CH₂CH(OD)CH₂CH₂CH₃)(OD₂)^(4-)

Downstream raw materials:

dimethyl-(2-hydroxy-pentyl)-amine

1,2-pentanediol

bis-(2-hydroxy-pentyl)-ether

pentanal

Refernces

• 1、 Zou,Sun,Chen. "Synthesis and Crystal Structures of Oxidovanadium(V) Complexes Derived from Hydrazones with the Catalytic Property". . p. 1101 - 1109. Retrieved 2019.
• 2、 Scheick,Spiteller. "Genesis and metabolisation of 1-pentene during lipid peroxidation of ω-6 unsaturated fatty acids: Metabolism of 1-pentene". . p. 63 - 68. Retrieved 1996.
• 3、 Liu,Zang,Lv. "Synthesis, structure, and catalytic oxidation of a molybdenum(VI) complex [MoO2(CH3OH)L]". . p. 451 - 455. Retrieved 2015.
• 4、 Shen, Yirui,Jiang, Pingping,Wang, Yingchun,Bian, Gang,Wai, Phyu Thin,Dong, Yuming. "MoO3@SiO2 nanoreactors: Synthesis with a thermal decomposition strategy and catalysis on alkenes epoxidation". . p. 156 - 164. Retrieved 2018.
• 5、 Bouchoux, Guy,Djazi, Feycal,Hoppilliard, Yannik,Jaudon, Pascale,Nouts, Nathalie. "Dissociation of Positively Charged Aliphatic Epoxides. II. +. Epoxides and α,β Unsaturated Ethers". . p. 33 - 41. Retrieved 1988.
• 6、 Jiang, Jingang,Tian, Wenwen,Wang, Bowen,Wu, Peng,Xu, Hao,Yin, Jianyong,Yin, Jinpeng. "Highly selective 1-pentene epoxidation over Ti-MWW with modified microenvironment of Ti active sites". . p. 6050 - 6064. Retrieved 2020.
• 7、 Cheng, Maosheng,Fan, Zhanfang,Lin, Bin,Liu, Yang,Liu, Yongqing. "Immobilization of molybdenum-based complexes on dendrimer-functionalized graphene oxide and their catalytic activity for the epoxidation of alkenes". . . Retrieved 2021.
• 8、 Emmons,Pagano. "-". . p. 89,92. Retrieved 1955.
• 9、 Rybina,Srednev,Bobyleva. "Synthesis of Cyclic Organic Carbonates from C3-C16 Epoxides". . p. 842 - 843. Retrieved 2003.
• 10、 Zhang, Jian,Jiang, Pingping,Shen, Yirui,Zhao, Guohu,Zhang, Weijie,Bian, Gang. "Co-Condensation Assisted Preparation of MoVI Schiff Base Modified Mesoporous Silica Catalyst for Enhanced Epoxidation of Olefins". . p. 817 - 825. Retrieved 2016.