(Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂

Base Information

• Chemical Name: (Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂
• CAS No.: 1025766-55-5
• Molecular Formula: C₁₇H₂₂Cl₂O₃P₂Pd
• Molecular Weight: 513.633
• Mol file: 1025766-55-5.mol

Synonyms:(Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂

Chemical Property of (Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂

There total 2 articles about (Ph₂PCH₂P(O)(OEt)2-P,O)PdCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + (CH3)3SiCH(P(C6H5)2)PO(OCH2CH3)2 (1025766-54-4) → (Ph2PCH2P(O)(OEt)2-P,O)PdCl2 (1025766-55-5) + (μ-Ph2PCH2P(O)(OEt)2)2Pd2Cl5Li*4chloroform

Guidance literature:

With H₂O; In dichloromethane; byproducts: C8H12; reaction of palladium compd. with phosphonatophosphine deriv. in CH2Cl2 at room temp. for 1 h; NMR and IR;

DOI:10.1021/ic800355m

Reference yield: 54.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + chloroform (67-66-3,8013-54-5) + (CH3)3SiCH(P(C6H5)2)PO(OCH2CH3)2 (1025766-54-4) + lithium chloride → (Ph2PCH2P(O)(OEt)2-P,O)PdCl2 (1025766-55-5) + (μ-Ph2PCH2P(O)(OEt)2)2Pd2Cl5Li*4chloroform

Guidance literature:

With H₂O; In dichloromethane; byproducts: C8H12; reaction of palladium compd. with phosphonatophosphine deriv. in CH2Cl2 in presence of LiCl at room temp.; elem. anal.;

DOI:10.1021/ic800355m

upstream raw materials:

dichloro(1,5-cyclooctadiene)palladium(II)

chloroform

(CH₃)3SiCH(P(C₆H₅)2)PO(OCH₂CH₃)2