3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Base Information

• Chemical Name: 3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• CAS No.: 1401439-72-2
• Molecular Formula: C₁₁₃H₁₂₁Cl₆N₅O₃₅
• Molecular Weight: 2321.93
• Mol file: 1401439-72-2.mol

Synonyms:3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property of 3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

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Useful:

Technology Process of 3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

There total 1 articles about 3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (646058-15-3) + p-tolyl 4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranoside + p-tolyl (methyl 4,7,8,9-tetra-O-acetyl-3,5-dideoxy-5-trichloroacetamido-D-glycero-α-D-galacto-2-nonulopyranosylonate-(2->3))-2-O-benzoyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside (1071226-23-7) → 3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (1401439-72-2)

Guidance literature:

p-tolyl (methyl 4,7,8,9-tetra-O-acetyl-3,5-dideoxy-5-trichloroacetamido-D-glycero-α-D-galacto-2-nonulopyranosylonate-(2->3))-2-O-benzoyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

With silver trifluoromethanesulfonate; In dichloromethane; acetonitrile; at -78 ℃; for 0.0833333h; Inert atmosphere;

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside; p-tolyl 4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranoside; Further stages;

DOI:10.1016/j.tetlet.2012.08.077

Reference yield:

3-azidopropyl (methyl 5-trichloroacetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)-2-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1→3)-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-1-thio-β-D-galactopyranosyl-(1→4)-2,3,6-tri-Obenzyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (1401439-72-2) → C51H73N5O27

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; at 50 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.08.077

upstream raw materials:

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

p-tolyl (methyl 4,7,8,9-tetra-O-acetyl-3,5-dideoxy-5-trichloroacetamido-D-glycero-α-D-galacto-2-nonulopyranosylonate-(2->3))-2-O-benzoyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside