5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride

Base Information

• Chemical Name: 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride
• CAS No.: 226922-75-4
• Molecular Formula: C₃₇H₈ClF₁₅FeN₄
• Molecular Weight: 884.773
• Mol file: 226922-75-4.mol

Synonyms:5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride

Chemical Property of 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride

There total 7 articles about 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + Fe(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)2 (340165-39-1) → 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride (226922-75-4)

Guidance literature:

In dichloromethane; water; CH2Cl2 soln. of Fe complex washed with dilute HCl in H2O;

DOI:10.1039/c2cc30580a

Reference yield: 80.0%

iron(II) chloride tetrahydrate + 5,10,15-tris(pentafluorophenyl)corrole → 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride (226922-75-4)

Guidance literature:

In N,N-dimethyl-formamide; at 140 ℃; for 1.5h; Schlenk technique; Inert atmosphere; Darkness;

DOI:10.1021/acs.organomet.5b00069

Reference yield: 68.0%

iron(II) chloride tetrahydrate + 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6) → 5,10,15-tris(pentafluorophenyl)corrole iron(IV) chloride (226922-75-4)

Guidance literature:

In N,N-dimethyl-formamide; for 4h; Reflux; Inert atmosphere; Darkness;

DOI:10.1007/s11243-019-00307-5

upstream raw materials:

hydrogenchloride

(5,10,15-tris(pentafluorophenyl)corrolato)iron(III)

Fe^III(5,10,15-tripentafluorophenylcorrole trianion)(diethyl ether)₂

5,10,15-tris(pentafluorophenyl)corrole

Downstream raw materials:

[Fe(5,10,15-tris(pentafluorophenyl)corrolate)(NO)]

[(Fe((O2N)2TF5PC))2(μ-oxo)]

(5,10,15-tris(pentafluorophenyl)corrolato)iron(III)

[Fe(5,10,15-tris(pentafluorophenyl)corrolato)(nitrato)]