methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

Base Information

Chemical Name:methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside
CAS No.:366801-70-9
Molecular Formula:C₃₂H₃₆O₉S
Molecular Weight:596.698
Hs Code.:

Synonyms:methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

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Technology Process of methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

There total 3 articles about methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 623-68-7
trans-crotonic anhydride

: 54522-57-5
methyl-2,3-di-O-benzyl-6-O-(4-toluenesulfonyl)-α-D-glucopyranoside

: 366801-70-9
methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 23h;
DOI:10.1021/jo0101860

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 366801-70-9
methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / pyridine; 4-dimethylaminopyridine / CH₂Cl₂ / 19.5 h

2: 98 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 23 h

With pyridine; dmap; triethylamine; In dichloromethane;
DOI:10.1021/jo0101860

Reference yield:

: 17791-36-5
methyl 2,3-di-O-benzyl-α-D-glucopyranoside

: 366801-70-9
methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / pyridine; 4-dimethylaminopyridine / CH₂Cl₂ / 19.5 h

2: 98 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 23 h

With pyridine; dmap; triethylamine; In dichloromethane;
DOI:10.1021/jo0101860