di[(μ-N,N'-dibenzylethylenediamide)germanium(II)]

Base Information

• Chemical Name: di[(μ-N,N'-dibenzylethylenediamide)germanium(II)]
• CAS No.: 1232692-08-8
• Molecular Formula: C₃₂H₃₆Ge₂N₄
• Molecular Weight: 621.845
• Mol file: 1232692-08-8.mol

Synonyms:di[(μ-N,N'-dibenzylethylenediamide)germanium(II)]

Chemical Property of di[(μ-N,N'-dibenzylethylenediamide)germanium(II)]

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of di[(μ-N,N'-dibenzylethylenediamide)germanium(II)]

There total 1 articles about di[(μ-N,N'-dibenzylethylenediamide)germanium(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

bis[bis(trimethylsilyl)amino]germanium(II) (59863-12-6) + N,N'-Dibenzylethylenediamine (140-28-3,87170-83-0) → di[(μ-N,N'-dibenzylethylenediamide)germanium(II)] (1232692-08-8)

Guidance literature:

In toluene; byproducts: (Si(CH3)3)2NH; (Ar), 1 equiv. of ligand in toluene added dropwise to a stirred soln. ofGe complex in toluene, stirred for 10 min; slowly crystd. at room temp., elem. anal.;

DOI:10.1002/ejic.200900556

Reference yield:

di[(μ-N,N'-dibenzylethylenediamide)germanium(II)] (1232692-08-8) → germanium (7440-56-4)

Guidance literature:

In further solvent(s); dried Ge complex dissolved in oleylamine injected to soln. of octadecenepreheated to 315°C, heated at this temp. for 30 min; cooled to room temp., dissolved in CHCl3, pptd.(CH3OH), centrifuged, repeated this washing 3 times, dispersed in CHCl3;

DOI:10.1002/ejic.200900556

upstream raw materials:

bis[bis(trimethylsilyl)amino]germanium(II)

N,N'-Dibenzylethylenediamine

Downstream raw materials:

germanium