(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

Base Information

Chemical Name:(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol
CAS No.:177600-54-3
Molecular Formula:C₄₀H₇₈O₅Si₃
Molecular Weight:723.313
Hs Code.:

Synonyms:(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

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Chemical Property of (E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

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Technology Process of (E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

There total 6 articles about (E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-enoic acid ethyl ester

: 177600-54-3
(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃; Yield given;
DOI:10.1039/CC9960001027

Reference yield:

: 994-30-9
triethylsilyl chloride

: 177600-54-3
(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole, DMAP / CH₂Cl₂

2: DIBAL-H / toluene / -78 °C

With 1H-imidazole; dmap; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1039/CC9960001027

Reference yield:

: 177929-77-0
(E)-3-[(2S,3S)-3-((1R,2R,3R,4R,5R)-6-Benzyloxy-2,4-dihydroxy-1,3,5-trimethyl-hexyl)-oxiranyl]-acrylic acid ethyl ester

: 177600-54-3
(E)-(4R,5R,6S,7S,8R,9R,10R)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undec-2-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / H₂O / 1,2-dichloro-ethane / -30 °C

2: imidazole, DMAP / CH₂Cl₂

3: DIBAL-H / toluene / -78 °C

With 1H-imidazole; dmap; water; diisobutylaluminium hydride; In dichloromethane; 1,2-dichloro-ethane; toluene;
DOI:10.1039/CC9960001027