2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

Base Information

Chemical Name:2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose
CAS No.:122822-10-0
Molecular Formula:C₄₃H₆₀O₇Si₂
Molecular Weight:745.116
Hs Code.:

2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

Synonyms:2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

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Chemical Property of 2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

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Technology Process of 2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

There total 6 articles about 2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 122822-10-0
2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / imidazole / dimethylformamide / 0.5 h / 0 °C

2: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) 0 deg C, 10 min

With 1H-imidazole; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In N,N-dimethyl-formamide;
DOI:10.1021/ja00199a031

Reference yield:

: 122822-08-6
2,6:5,9:8,12-Trianhydro-4-O-benzyl-1-O-(tert-butyldiphenylsilyl)-3,7,10-trideoxy-5-C-methyl-D-allo-D-altro-tridecitol

: 122822-10-0
2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / imidazole / dimethylformamide / 0.5 h / 0 °C

2: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) 0 deg C, 10 min

With 1H-imidazole; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In N,N-dimethyl-formamide;
DOI:10.1021/ja00199a031

Reference yield:

: 122822-04-2
Methy (E)-4,8:7,11:10,14-trianhydro-12-O-benzyl-15-O-(tert-butyldiphenylsilyl)-2,3,6,9,13-pentadeoxy-11-C-methyl-D-talo-L-allo-pentadec-2-enonate

: 122822-10-0
2,6:5,9:8,12-Trianhydro-10-O-benzyl-1-O-(tert-butyldimethylsilyl)-13-O-(tert-butyldiphenylsilyl)-4,7,11-trideoxy-9-C-methyl-D-threo-L-allo-L-glycero-3-trideculose

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) ozone, 2.) Me₂S, Ph₃P, NaBH₄ / 1.) CH₂Cl₂, -78 deg C, 2.) MeOH, r.t., 1 h

2: 91 percent / imidazole / dimethylformamide / 0.5 h / 0 °C

3: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) 0 deg C, 10 min

With 1H-imidazole; sodium tetrahydroborate; oxalyl dichloride; dimethylsulfide; ozone; dimethyl sulfoxide; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1021/ja00199a031