benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

Base Information

Chemical Name:benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside
CAS No.:164215-16-1
Molecular Formula:C₆₉H₇₂O₁₁
Molecular Weight:1077.32
Hs Code.:

Synonyms:benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

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Chemical Property of benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

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Technology Process of benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

There total 6 articles about benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 125219-23-0
Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(formyl)-α-D-glucopyranoside

: 164215-16-1
benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA / 1.) THF, HMPT, -100 deg C, 30 min, 2.) THF, HMPT, 60 min

2: 87 percent / Raney nickel W II / tetrahydrofuran / 0.5 h

3: 1.) H₃B*SMe₂, 2.) 10percent NaOH, 35percent H₂O₂ / 1.) THF, 4 deg C, 3 d, 2.) THF, H₂O, 30 min

4: 1.) NaH / 1.) DMF, r.t., 1 h, 2.) DMF, -10 deg C, 10 h

With sodium hydroxide; dimethylsulfide borane complex; Raney nickel W II; dihydrogen peroxide; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran;

Reference yield:

: 125710-64-7
1,5-anhydro-3,4,6-tri-O-benzyl-1,2-dideoxy-2-((S)-phenylsulfinyl)-D-lyxo-hex-1-enitol

: 164215-16-1
benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA / 1.) THF, HMPT, -100 deg C, 30 min, 2.) THF, HMPT, 60 min

2: 87 percent / Raney nickel W II / tetrahydrofuran / 0.5 h

3: 1.) H₃B*SMe₂, 2.) 10percent NaOH, 35percent H₂O₂ / 1.) THF, 4 deg C, 3 d, 2.) THF, H₂O, 30 min

4: 1.) NaH / 1.) DMF, r.t., 1 h, 2.) DMF, -10 deg C, 10 h

With sodium hydroxide; dimethylsulfide borane complex; Raney nickel W II; dihydrogen peroxide; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran;

Reference yield:

: 164323-20-0
benzyl 4-C-<2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-3-<(R)-phenylsulfinyl>-D-galacto-hept-2-enit-1-yl>-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

: 164215-16-1
benzyl 4-C-(2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-threo-L-talo-heptit-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / Raney nickel W II / tetrahydrofuran / 0.5 h

2: 1.) H₃B*SMe₂, 2.) 10percent NaOH, 35percent H₂O₂ / 1.) THF, 4 deg C, 3 d, 2.) THF, H₂O, 30 min

3: 1.) NaH / 1.) DMF, r.t., 1 h, 2.) DMF, -10 deg C, 10 h

With sodium hydroxide; dimethylsulfide borane complex; Raney nickel W II; dihydrogen peroxide; sodium hydride; In tetrahydrofuran;