125710-64-7

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 13265-84-4 D-glucal 
• 125710-62-5 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-D-lyxo-hex-1-enitol 
• 100-39-0 benzyl bromide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 116454-02-5 1,5-Anhydro-3,4,6-tri-O-benzyl-1,2-didesoxy-2-phenylthio-D-arabino-hex-1-enitol 
• 80040-79-5 3,4,6-tri-O-benzyl-D-galactal 

Downstream Products

• 125612-03-5 3,7-anhydro-5,6,8-tri-O-benzyl-4-deoxy-4-phenylsulfinyl-D-talo-oct-3-enose diethylacetal 
• 125612-03-5 3,7-anhydro-5,6,8-tri-O-benzyl-4-deoxy-4-phenylsulfinyl-D-galacto-oct-3-enose diethylacetal 
• 118798-68-8 2,6-Anhydro-1,3,4-tri-O-benzyl-5,8,9-tridesoxy-5-phenylsulfinyl-D-manno-non-5-enitol 
• 118798-68-8 2,6-Anhydro-1,3,4-tri-O-benzyl-5,8,9-tridesoxy-5-phenylsulfinyl-L-gulo-non-5-enitol 
• 118798-71-3 2,6-Anhydro-1,3,4-tri-O-benzyl-5-desoxy-8,9:10,11-di-O-isopropyliden-5-phenylsulfinyl-D-manno-D-arabino-undec-5-enitol 
• 118798-71-3 2,6-Anhydro-1,3,4-tri-O-benzyl-5-desoxy-8,9:10,11-di-O-isopropyliden-5-phenylsulfinyl-L-gulo-D-arabino-undec-5-enitol 
• 158382-72-0 2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-3-(S)-phenylsulfinyl-aldehydo-D-lyxo-hept-2-enose 
• 164323-19-7 benzyl 4-C-<2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-3-<(R)-phenylsulfinyl>-D-talo-hept-2-enit-1-yl>-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside 
• 164323-20-0 benzyl 4-C-<2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-3-<(R)-phenylsulfinyl>-D-galacto-hept-2-enit-1-yl>-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside 
• 116454-09-2 5,7-Di-O-acetyl-2,6-anhydro-1,3,4-tri-O-benzyl-8,9-didesoxy-L-gulo-D-threo-nonitol 
• 118916-55-5 5,7-Di-O-acetyl-2,6-anhydro-1,3,4-tri-O-benzyl-8,9-didesoxy-L-gulo-L-erythro-nonitol 
• 116558-80-6 2,6-Anhydro-1,3,4-tri-O-benzyl-8,9-didesoxy-5,7-isopropyliden-L-gulo-D-erythro-nonitol 
• 116454-11-6 2,6-Anhydro-1,3,4-tri-O-benzyl-8,9-didesoxy-5,7-isopropyliden-L-gulo-D-threo-nonitol 
• 116558-79-3 2,6-Anhydro-1,3,4-tri-O-benzyl-8,9-didesoxy-L-gulo-L-erythro-nonitol 

Relevant academic research and scientific papers

SYNTHESIS OF CARBON BRIDGED C-DISACCHARIDES

Direct lithiation of the readily available 2-phenylsulfinyl-D-glucal 2 provides the 1-C-lithiated species 2A furnishing with 4-deoxy-4-formyl-D-glucose derivative 7 in a diastereocontrolled reaction the C-disaccharide intermediate 8.This compound is trans

Synthesis of the basic structure of Ezomycin A

Direct 1-C-lithiation of the readily available 2-phenylsulfinyl-D-galactals 3h, l leads to reactive intermediate, which on reaction with glyoxal monodiethylacetal as electrophile yield compounds 7.Subsequent O-benzylation of the unprotected hydroxy group,

Functionally Substituted Vinyl Carbanions, 38. - C-Glucosides by Direct 1-C-Lithiation of 2-Phenylsulfinyl-Activated D-Glucal

Direct 1-C-lithiation of the readily available 2-phenylsulfinyl-D-glucals 6,h,l leads to reactive intermediates furnishing with aldehydes as electrophiles the compounds 7 in high yields.Subsequent removal of the phenylsulfinyl group with Raney nickel and