Technology Process of 9-Dioctylamino-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide
There total 4 articles about 9-Dioctylamino-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate;
In
toluene;
at 90 ℃;
DOI:10.1039/c1gc15864c
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1H-imidazole; zinc(II) acetate dihydrate / water / 20 h / 190 °C / Autoclave
2: bromine; potassium carbonate / chlorobenzene / 2.5 h / 40 - 50 °C
3: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate / toluene / 90 °C
With
1H-imidazole; tris-(dibenzylideneacetone)dipalladium(0); bromine; zinc(II) acetate dihydrate; potassium carbonate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate;
In
water; chlorobenzene; toluene;
3: Hartwig-Buchwald amination;
DOI:10.1039/c1gc15864c
- Guidance literature:
-
Multi-step reaction with 2 steps
1: bromine; potassium carbonate / chlorobenzene / 2.5 h / 40 - 50 °C
2: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate / toluene / 90 °C
With
tris-(dibenzylideneacetone)dipalladium(0); bromine; potassium carbonate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate;
In
chlorobenzene; toluene;
2: Hartwig-Buchwald amination;
DOI:10.1039/c1gc15864c