Synonyms:Sulphasolucin;Soluseptazine;RP-40;Solucin;1-phenyl-3-(4-sulfamoyl-anilino)-propane-1,3-disulfonic acid,disodium-salt;Solusetazine;Sulseptasine;1-Phenyl-3-(4-sulfamoyl-anilino)-propan-1,3-disulfonsaeure,Dinatrium-Salz;
99% *data from raw suppliers
NOPRYLSULFAMIDE 95.00% *data from reagent suppliers
There total 2 articles about Sulphasolucin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
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The study conducted by Roland Appel, Nicolai Hartmann, and Herbert Mayr from the Department of Chemistry at Ludwig-Maximilians-Universit?t München, investigates the cyclopropanation reactions using sulfur ylides. It focuses on the rates of reactions between stabilized and semistabilized sulfur ylides with benzhydrylium ions and Michael acceptors, measured using UV-vis spectroscopy in DMSO at 20°C. The research establishes a correlation between the second-order rate constants (log k2) and the electrophilicity parameters (E) of the electrophiles, which aids in calculating the nucleophile-specific parameters (N and s) for the sulfur ylides. The findings indicate that the rate constants for cyclopropanation reactions with Michael acceptors align with those for carbocations, suggesting a stepwise mechanism with the initial nucleophilic attack being rate-determining. This study provides a quantitative approach to understanding sulfur ylide reactivity, which is crucial for predicting the scope and limitations of cyclopropanation reactions in organic synthesis.
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