[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

Base Information

Chemical Name:[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)
CAS No.:623938-44-3
Molecular Formula:C₂₃H₃₀NNiO₂P
Molecular Weight:442.16
Hs Code.:

Synonyms:[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

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Chemical Property of [2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

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Technology Process of [2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

There total 2 articles about [2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: (η3-benzyl)chloro(trimethylphosphine)nickel(II)

: 60054-57-1
2-(cyclohexylideneamino)benzoic acid

: 623938-44-3
[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

Guidance literature:: With KH; In tetrahydrofuran; under inert atm. 2-(cyclohexylideneamino)benzoic acid and KH were stirred in THF overnight at room temp., Ni complex was added and stirred for 1h; solvent was removed under vac., residue was dissolved in toluene, soln. was filtered, solvent was removed, residue was triturated in pentane; elem. anal.;
DOI:10.1021/om0303303

Reference yield:

: 100-44-7
benzyl chloride

: 623938-44-3
[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: KH / tetrahydrofuran

With KH; In tetrahydrofuran;
DOI:10.1021/om0303303

Reference yield: 85.0%

: 623938-44-3
[2-(cyclohexylideneamino)benzoato-κ(2)N,O](η1-benzyl)(trimethylphosphine)nickel(II)

: 1109-15-5
tris(pentafluorophenyl)borate

: 220169-11-9
(Me₃P)B(C₆F₅)3

: [(2-(cyclohexylideneamino)benzoato)tris(pentafluorophenyl)borato-κ(2)N,O](η13benzyl)nickel(II)

Guidance literature:: In toluene; under inert atm. Ni complex and B(C6F5)3 in cold toluene (-30°C) were stirred for 30 min; ppt. was filtered off, solvent was removed, residue was triturated with pentane and dried in vacuo;
DOI:10.1021/om0303303