(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

Base Information

Chemical Name:(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester
CAS No.:853645-39-3
Molecular Formula:C₂₆H₃₅ClO₇
Molecular Weight:495.013
Hs Code.:

Synonyms:(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

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Chemical Property of (R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

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Technology Process of (R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

There total 6 articles about (R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 853645-31-5
hepta-2,6-dienoic acid methoxy-methylamide

: 853645-37-1
(R)-(-)-3-chloro-4,6-bis-ethoxymethoxy-2-methylbenzoic acid 1-methylbut-3-enyl ester

: 853645-39-3
(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

Guidance literature:: (R)-(-)-3-chloro-4,6-bis-ethoxymethoxy-2-methylbenzoic acid 1-methylbut-3-enyl ester; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃;

hepta-2,6-dienoic acid methoxy-methylamide; In tetrahydrofuran; at -78 ℃; for 0.166667h;
DOI:10.1021/ja043101w

Reference yield:

: 853645-35-9
3-chloro-4,6-dihydroxy-2-methylbenzoic acid 1-methylbut-3-enyl ester

: 853645-39-3
(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: diisopropylethylamine / tetrabutylammonium iodide / dimethylformamide / 5 h / 80 °C

2: lithium diisopropylamide / tetrahydrofuran / 0.17 h / -78 °C

With N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/chem.200600553

Reference yield:

: 480-64-8
orsellinic acid

: 853645-39-3
(R)-(+)-3-chloro-4,6-bis-ethoxymethoxy-2-(2-oxoocta-3,7-dienyl)benzoic acid 1-methylbut-3-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / NaClO₂; sulfamic acid; acetaldehyde / tetrahydrofuran; H₂O / 0.5 h / 0 °C

2: tris(3-chlorophenyl)phosphine; ethoxycarbonylazocarboxymethyl polystyrene / CH₂Cl₂ / 0.5 h / 23 °C

3: diisopropylethylamine / tetrabutylammonium iodide / dimethylformamide / 5 h / 80 °C

4: lithium diisopropylamide / tetrahydrofuran / 0.17 h / -78 °C

With sodium chlorite; ethoxycarbonylazocarboxymethyl polystyrene; tri(m-chlorophenyl)-phosphine; aminosulfonic acid; acetaldehyde; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/chem.200600553