2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

Base Information

Chemical Name:2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde
CAS No.:97826-92-1
Molecular Formula:C₁₇H₂₀O₄
Molecular Weight:288.343
Hs Code.:

Synonyms:2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

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Chemical Property of 2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

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Technology Process of 2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

There total 4 articles about 2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 97905-62-9
2(S)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranemethanol

: 97826-92-1
2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; Yield given. Multistep reaction; 1. CH₂Cl₂, -55 deg C 2. -55 deg C up to 25 deg C;
DOI:10.1021/jo00294a030

Reference yield:

: 124603-86-7
cis-2-<2-<(4-methoxybenzyl)oxy>-3-cyclohexen-1-yl>-2-propen-1-ol 1-acetate

: 97826-92-1
2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: K₂CO₃ / methanol / 25 °C

2: t-BuOOH, (+)-diethyl tartarate, Ti(O-t-Bu)4 / CH₂Cl₂ / 5.5 h / -23 °C

3: oxalyl chloride / dimethylsulfoxide / -60 °C

With titanium(IV) tetrabutoxide; tert.-butylhydroperoxide; oxalyl dichloride; potassium carbonate; (+)-Weinsaeure-diethylester; In methanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00218a039

Reference yield:

: 97826-91-0
cis-2-<2-<(4-methoxybenzyl)oxy>-3-cyclohexen-1-yl>-2-propen-1-ol

: 97826-92-1
2(R)-<2(R)-<(4-methoxybenzyl)oxy>-3-cyclohexen-1(S)-yl>oxiranecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: t-BuOOH, (+)-diethyl tartarate, Ti(O-t-Bu)4 / CH₂Cl₂ / 5.5 h / -23 °C

2: oxalyl chloride / dimethylsulfoxide / -60 °C

With titanium(IV) tetrabutoxide; tert.-butylhydroperoxide; oxalyl dichloride; (+)-Weinsaeure-diethylester; In dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00218a039