bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au)

Base Information

• Chemical Name: bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au)
• CAS No.: 89462-48-6
• Molecular Formula: C₂₉H₃₁Au₂BrP₂
• Molecular Weight: 915.35
• Mol file: 89462-48-6.mol

Synonyms:bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au)

Chemical Property of bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au)

There total 1 articles about bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

gold(I)-dimethylphosphoniumbis(methylide) dimer → bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au) (89462-48-6)

Guidance literature:

With methyl bromide; In benzene; The mixt. of reagents (excess of MeBr) in benzene was stirred overnightat 25°C (N2 atm.;; evapd. to dryness;;

DOI:10.1021/ja00310a028

Reference yield:

bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au) (89462-48-6) → Au2(CH2P(C6H5)2CH2)2I2

Guidance literature:

Multi-step reaction with 3 steps

1: neat (no solvent)

2: methyl iodide / toluene

3: chloroform-d1

With methyl iodide; In chloroform-d1; toluene;

DOI:10.1021/ja00310a028

Reference yield:

bis[μ-(diphenyldimethylenephosphoranyl-C,C)]bromomethyldigold(II)(Au-Au) (89462-48-6) → [Au2Cl2(μ-(CH2)2PPh2)2]

Guidance literature:

Multi-step reaction with 2 steps

1: neat (no solvent)

2: CCl₄ / tetrachloromethane

With CCl₄; In tetrachloromethane;

DOI:10.1021/ja00310a028

Downstream raw materials:

bis[μ-(diphenyldimethylenephosphoranyl-C,C)]iodotrideuteriomethyldigold(II)(Au-Au)

bis[μ-(diphenyldimethylenephosphoranyl-C,C)]iodo((trimethylsilyl)methyl)digold(II)(Au-Au)

bis[μ-(diphenyldimethylenephosphoranyl-C,C)]benzylbromodigold(II)(Au-Au)