Decyl 4-nitrophenyl ether

Base Information

• Chemical Name: Decyl 4-nitrophenyl ether
• CAS No.: 31657-37-1
• Molecular Formula: C16H25NO3
• Molecular Weight: 279.379
• Hs Code.: 2909309090
• European Community (EC) Number: 653-215-2
• DSSTox Substance ID: DTXSID70185550
• Wikidata: Q83056595
• Mol file: 31657-37-1.mol

Synonyms:Decyl 4-nitrophenyl ether;31657-37-1;P-DECYLOXYNITROBENZENE;1-decoxy-4-nitrobenzene;1-(Decyloxy)-4-nitrobenzene;p-Nitrophenyl decyl ether;4-decyloxynitrobenzene;SCHEMBL5049067;1-(Decyloxy)-4-nitrobenzene #;DTXSID70185550;AKOS025116675;AS-57855;FT-0762448;D96046

Chemical Property of Decyl 4-nitrophenyl ether

Chemical Property:

• Vapor Pressure: 4.43E-06mmHg at 25°C
• Refractive Index: 1.504
• Boiling Point: 394.7 °C at 760 mmHg
• Flash Point: 145.5 °C
• PSA: 55.05000
• Density: 1.02 g/cm³
• LogP: 5.63750
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 10
• Exact Mass: 279.18344366
• Heavy Atom Count: 20
• Complexity: 245

Purity/Quality:

98%Min ^*data from raw suppliers

DECYL 4-NITROPHENYL ETHER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCOC1=CC=C(C=C1)[N+](=O)[O-]

Technology Process of Decyl 4-nitrophenyl ether

There total 7 articles about Decyl 4-nitrophenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 1-bromo dodecane (112-29-8) → decyl 4-nitrophenyl ether (31657-37-1)

Guidance literature:

With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; at 90 ℃; for 8h;

DOI:10.1002/anie.201407497

Reference yield: 61.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + Iododecane (2050-77-3) → decyl 4-nitrophenyl ether (31657-37-1)

Guidance literature:

With potassium carbonate; In acetone; for 71h; Heating;

DOI:10.1002/poc.1148

Reference yield:

C17H24F3NO6S → decyl 4-nitrophenyl ether (31657-37-1)

Guidance literature:

With 1,1,3,3-Tetramethyldisiloxane; [1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene]copper(I) tert-butoxide; cesium fluoride; In 1,4-dioxane; at 25 ℃; for 4h; Glovebox; Inert atmosphere;

DOI:10.1002/anie.201307697

upstream raw materials:

4-nitro-phenol

1-bromo dodecane

4-nitrophenol sodium salt

Iododecane

Downstream raw materials:

C₃₄H₅₂N₂O₃S

4-hydroxy-4′-n-decyloxyazobenzene

4,4'-decyloxyazoxybenzene

(E)-4,4'-dimethylazobenzene

Refernces

• 1、 Rezvani, Zolfaghar,Nejati, Kamellia,Seyedahmadian, Masoud,Divband, Baharak. "Investigation of liquid crystalline behavior of copper(II) complexes derived from Azo-containing salicylaldimine ligands with lateral hydroxyl group". . p. 71 - 81. Retrieved 2008.
• 2、 Hautala,R.R.,Letsinger,R.L.. "-". . p. 3762 - 3768. Retrieved 1971.
• 3、 ?a?lar, Fatma P?nar,Akda?-K?l??, Huriye,Eran, Belk?z Bilgin,Ocak, Hale. "Chiral polymorphism in new imine based rod-like liquid crystals". . . Retrieved 2020/07/06.
• 4、 Lei, Zih-Yang,Lee, Gene-Hsiang,Lai, Chung K.. "Luminescent mesogenic borondifluoride complexes with the Schiff bases containing salicylideneamines and β-enaminoketones core systems". . p. 44 - 56. Retrieved 2018/04/02.