benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

Base Information

Chemical Name:benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside
CAS No.:174151-34-9
Molecular Formula:C₂₉H₃₀BrNO₉S
Molecular Weight:648.529
Hs Code.:

Synonyms:benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

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Chemical Property of benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

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Technology Process of benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

There total 1 articles about benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 2864-17-7
benzyl O⁴,O⁶-(R)-benzylidene-2-benzyloxycarbonylamino-O³-methanesulfonyl-α-D-2-deoxy-glucopyranoside

: 174151-34-9
benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

Guidance literature:: With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; for 2h; Heating;
DOI:10.1016/0008-6215(95)00291-X

Reference yield: 84.0%

: 174151-34-9
benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

: 174151-35-0
benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

Guidance literature:: With azobisisobutyronitrile; tri-n-butyl-tin hydride; In benzene; for 3h; Heating;
DOI:10.1016/0008-6215(95)00291-X

Reference yield:

: 174151-34-9
benzyl 4-O-benzoyl-2-benzyloxycarbonylamino-6-bromo-2,6-dideoxy-3-O-methanesulfonyl-α-D-glucopyranoside

: benzyl 3-amino-2-benzyloxycarbonylamino-2,3,6-trideoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / tributyltin hydride, α,α'-azobisisobutyronitrile / benzene / 3 h / Heating

2: K₂CO₃ / methanol / 4 h / Ambient temperature

3: NaH / tetrahydrofuran

4: 13 percent / NaN₃, NH₄Cl / ethanol; H₂O / 22 h / Heating

5: NaBH₄, NiCl₂ / ethanol / 0.75 h / Ambient temperature

With sodium tetrahydroborate; sodium azide; azobisisobutyronitrile; tri-n-butyl-tin hydride; sodium hydride; potassium carbonate; ammonium chloride; nickel dichloride; In tetrahydrofuran; methanol; ethanol; water; benzene;
DOI:10.1016/0008-6215(95)00291-X