trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

Base Information

Chemical Name:trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]
CAS No.:56629-93-7
Molecular Formula:C₂₁H₂₇ClCoN₄O₄P
Molecular Weight:524.89
Hs Code.:

trans-[Co(dimethylglyoximato<sup>(1-)</sup>)2(methyldiphenylphosphine)Cl]

Synonyms:trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

Suppliers and Price of trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

There total 1 articles about trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: chloridobis(dimethylglyoximate)(triphenylphosphane)cobalt(III)

: 1486-28-8
diphenyl(methyl)phosphine

: 56629-93-7
trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

Guidance literature:: In dichloromethane; byproducts: triphenylphosphine; N2-atmosphere; dropwise addn. of stoich. amt. of phosphine to Co-complex, stirring for 15 min; filtration, sepn. on addn. of Et2O, washing (Et2O), recrystn. (CH2Cl2/ether);
DOI:10.1016/S0020-1693(00)87270-9

Reference yield: 90.0%

: Na⁽¹⁺⁾*N₄C(C₆H₄F)^(1-) = NaN₄C(C₆H₄F)

: 56629-93-7
trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

: 74305-24-1
((CH₃)P(C₆H₅)2)Co(HONC(CH₃)C(CH₃)NO)2(N₄C(C₆H₄F))

Guidance literature:: In methanol; water; Co-complex dissolved with stirring and gentle heating in 80% MeOH, second soln. containing organic compound dissolved in warm H2O added dropwise to the first, soln. heated for 30 min, water added; refrigerated overnight, filtered with suction, washed with H2O, dried in air, complexe can recrystd. from warm DMF-H2O; elem. anal.;
DOI:10.1021/ja00529a017

Reference yield: 89.0%

: 56629-93-7
trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)Cl]

: 3425-46-5
potassium selenocyanate

: 66863-25-0
trans-[Co(dimethylglyoximato^(1-))2(methyldiphenylphosphine)(selenocyanate)]

Guidance literature:: In ethanol; dissoln. of Co-complex (room temp., stirring), slow addn. of equimolar amt. of KSeCN, stirring (room temp., 24 h); volume reduction (vac.), addn. to excess water (pptn.), filtration, drying (vac.); elem. anal.;
DOI:10.1016/S0020-1693(00)87270-9