(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

Base Information

Chemical Name:(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one
CAS No.:1198463-55-6
Molecular Formula:C₄₀H₅₄O₈
Molecular Weight:662.864
Hs Code.:

(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

Synonyms:(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

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Chemical Property of (1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

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Technology Process of (1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

There total 1 articles about (1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1198463-37-4
{(3S,4S,6R,1E)-3-(4-methoxybenzyloxy)-6-(methoxymethoxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]nona-1,8-dien-4-yl} (2Z)-4-{(2R,6R)-6-[(2S)-2-methylpent-4-ynyl]-5,6-dihydro-2H-pyran-2-yl}but-2-enoate

: 1198463-55-6
(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

Guidance literature:: With cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate; In acetone; at 50 ℃; for 0.25h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja907924j

Reference yield: 66.0%

: 1198463-55-6
(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

: 1198463-36-3
(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-hydroxy-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

Guidance literature:: With pyridinium p-toluenesulfonate; In tert-butyl alcohol; at 85 ℃; for 8h; Inert atmosphere;
DOI:10.1021/ja907924j

Reference yield:

: 1198463-55-6
(1R,3Z,7S,9S,10E,15S,17R)-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-9-(methoxymethoxy)-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,10,19-trien-5-one

: 1198463-35-2
(1R,3Z,7S,9E,11R,15S,17R)-11-hydroxy-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,9,19-trien-5-one

Guidance literature:: Multi-step reaction with 2 steps

1: pyridinium p-toluenesulfonate / tert-butyl alcohol / 8 h / 85 °C / Inert atmosphere

2: triphenylsilyl perrhenate / diethyl ether / 0.08 h / -50 °C / Inert atmosphere

With pyridinium p-toluenesulfonate; triphenylsilyl perrhenate; In diethyl ether; tert-butyl alcohol;
DOI:10.1002/chem.201102899