C₆₁H₉₆O₁₀SSi₂

Base Information

Chemical Name:C₆₁H₉₆O₁₀SSi₂
CAS No.:128329-87-3
Molecular Formula:C₆₁H₉₆O₁₀SSi₂
Molecular Weight:1077.66
Hs Code.:

C<sub>61</sub>H<sub>96</sub>O<sub>10</sub>SSi<sub>2</sub>

Synonyms:C₆₁H₉₆O₁₀SSi₂

Suppliers and Price of C₆₁H₉₆O₁₀SSi₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₆₁H₉₆O₁₀SSi₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₆₁H₉₆O₁₀SSi₂

There total 34 articles about C₆₁H₉₆O₁₀SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 128329-68-0,128440-44-8
(2R,3R,4S)-1-(benzyloxy)-2,4-dimethyl-3,5,6-hexanetriol

: 128329-87-3
C₆₁H₉₆O₁₀SSi₂

Guidance literature:: Multi-step reaction with 12 steps

1: 2.01 g / triethylamine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 12 h / 25 °C

2: 2.13 g / 2,2-dimethoxypropane, d,l-camphorsulfonic acid / 2 h / 25 °C

3: 1 N Bu₄NF / tetrahydrofuran / 10 h / 25 °C

4: 95 percent / triethylamine, SO₃*pyridine / dimethylsulfoxide / 0.75 h / 25 °C

5: 1.) sodium bis(trimethylsilyl)amide / 1.) toluene, 20 deg C, 15 min, 2a.) -78 deg C, 15 min, 2b.) 20 deg C, 30 min

6: 94 percent / Bu₄NF / tetrahydrofuran / 36 h / 80 °C

7: 1.) mercuric acetate, 2.) NaBH₄, 15percent aq. NaOH / 1.) CH₂Cl₂, 20 deg C, 7 h, 2.) MeOH, 20 deg C, 30 min

8: 100 percent / triethylamine / CH₂Cl₂ / 1.5 h / 0 °C

9: 94 percent / H₂ / 10percent Pd/C / acetone / 3 h / 20 °C / 760 Torr

10: oxalyl chloride, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

11: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 30 min, 2.) -78 deg C, 1 h

12: tetrahydrofuran; hexane / 1.5 h / 25 °C

With dmap; sodium hydroxide; sodium tetrahydroborate; n-butyllithium; oxalyl dichloride; pyridine-SO₃ complex; camphor-10-sulfonic acid; mercury(II) diacetate; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; dimethyl sulfoxide; triethylamine; 2,2-dimethoxy-propane; palladium on activated charcoal; In tetrahydrofuran; hexane; dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1021/ja00169a042

Reference yield:

: 128329-76-0
(1S,2R,5S,6R)-5-(3'-(benzyloxy)propyl)-1,2-dimethyl-4-methylene-3,9-dioxabicyclo<4.2.1>nonane

: 128329-87-3
C₆₁H₉₆O₁₀SSi₂

Guidance literature:: Multi-step reaction with 16 steps

1: 100 percent / pyridinium tosylate / CH₂Cl₂ / 6 h / 20 °C

2: 1.) ozone, 2.) dimethyl sulfide / 1.) CH₂Cl₂, -78 deg C, 2a.) -78 deg C, 1 h, 2b.) 20 deg C, 1 h

3: 55 percent / CH₂Cl₂; diethyl ether / 1.) -78 deg C, 8 h, 2.) 20 deg C, 2 h

4: 94 percent / triethylamine / CH₂Cl₂ / 2 h / 0 °C

5: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 19 h / 20 °C / 3040 Torr

6: 1.88 g / triethylamine / CH₂Cl₂ / 3 h / 0 °C

7: 1.84 g / NaI, NaHCO₃, diisopropylethylamine / acetone / 18 h / 20 °C

8: 78 percent / diisopropylethylamine / toluene; acetonitrile / 54 h / 75 °C

9: 1.) sodium bis(trimethylsilyl)amide / 1.) toluene, 20 deg C, 15 min, 2a.) -78 deg C, 15 min, 2b.) 20 deg C, 30 min

10: 94 percent / Bu₄NF / tetrahydrofuran / 36 h / 80 °C

11: 1.) mercuric acetate, 2.) NaBH₄, 15percent aq. NaOH / 1.) CH₂Cl₂, 20 deg C, 7 h, 2.) MeOH, 20 deg C, 30 min

12: 100 percent / triethylamine / CH₂Cl₂ / 1.5 h / 0 °C

13: 94 percent / H₂ / 10percent Pd/C / acetone / 3 h / 20 °C / 760 Torr

14: oxalyl chloride, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

15: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 30 min, 2.) -78 deg C, 1 h

16: tetrahydrofuran; hexane / 1.5 h / 25 °C

With sodium hydroxide; sodium tetrahydroborate; n-butyllithium; oxalyl dichloride; dimethylsulfide; mercury(II) diacetate; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; ozone; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; sodium iodide; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; ethyl acetate; acetone; toluene; acetonitrile;
DOI:10.1021/ja00169a042

Reference yield:

: 73814-77-4,108814-34-2
(3R,4S)-1-(benzyloxy)-3-hydroxy-4-(hydroxymethyl)-2-methyl-5-hexene

: 128329-87-3
C₆₁H₉₆O₁₀SSi₂

Guidance literature:: Multi-step reaction with 15 steps

1: 0.908 g / pyridine / 18 h / 5 °C

2: 0.468 g / lithium triethylborohydride / tetrahydrofuran / 24 h / 25 °C

3: 1.30 g / N-methylmorpholine N-oxide monohydrate, 0.16 M aq. osmium tetraoxide / acetone / 10 h / 25 °C

4: 2.01 g / triethylamine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 12 h / 25 °C

5: 2.13 g / 2,2-dimethoxypropane, d,l-camphorsulfonic acid / 2 h / 25 °C

6: 1 N Bu₄NF / tetrahydrofuran / 10 h / 25 °C

7: 95 percent / triethylamine, SO₃*pyridine / dimethylsulfoxide / 0.75 h / 25 °C

8: 1.) sodium bis(trimethylsilyl)amide / 1.) toluene, 20 deg C, 15 min, 2a.) -78 deg C, 15 min, 2b.) 20 deg C, 30 min

9: 94 percent / Bu₄NF / tetrahydrofuran / 36 h / 80 °C

10: 1.) mercuric acetate, 2.) NaBH₄, 15percent aq. NaOH / 1.) CH₂Cl₂, 20 deg C, 7 h, 2.) MeOH, 20 deg C, 30 min

11: 100 percent / triethylamine / CH₂Cl₂ / 1.5 h / 0 °C

12: 94 percent / H₂ / 10percent Pd/C / acetone / 3 h / 20 °C / 760 Torr

13: oxalyl chloride, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

14: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 30 min, 2.) -78 deg C, 1 h

15: tetrahydrofuran; hexane / 1.5 h / 25 °C

With pyridine; dmap; sodium hydroxide; sodium tetrahydroborate; osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; pyridine-SO₃ complex; camphor-10-sulfonic acid; mercury(II) diacetate; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; lithium triethylborohydride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; 2,2-dimethoxy-propane; palladium on activated charcoal; In tetrahydrofuran; hexane; dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1021/ja00169a042